Integrated Bench-Scale Parametric Study on CO2 Capture Using a Carbonic Anhydrase Promoted K2CO3 Solvent with Low Temperature Vacuum Stripping

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• 作者：Guojie Qi ; Kun Liu ; Reynolds A. Frimpong ; Alan House ; Sonja Salmon ; Kunlei Liu
• 刊名：Industrial & Engineering Chemistry Research
• 出版年：2016
• 出版时间：December 7, 2016
• 年：2016
• 卷：55
• 期：48
• 页码：12452-12459
• 全文大小：478K
• ISSN：1520-5045

文摘

A bench-scale unit was fabricated and used to investigate use of carbonic anhydrase (CA) promoted K₂CO₃ solvent as an option for CO₂ capture from coal-fired power plants. Bench-scale parametric tests were performed at various CA concentrations, solvent flow rates, and reboiler duties. The CO₂ capture efficiency significantly increases, and regeneration energy requirement decreases, with increasing CA concentrations up to 2.5 g/L, with capture performance leveling off at higher enzyme doses (up to 4 g/L). Thus, at higher enzyme doses, the capture efficiency is equilibrium rather than kinetically controlled at the top of absorber, when using solvent regenerated via vacuum stripping at high (>35%) lean carbonate to bicarbonate (CTB) conversion levels, which limits the driving force for CO₂ absorption. The CO₂ capture efficiency also increases when reboiler duty was increased from 0.85 to 1.1 kW, although this also increases the regeneration energy penalty. In contrast, the effect of solvent flow rate on CO₂ capture efficiency is less pronounced. Further improvements to the CO₂ capture process using CA promoted K₂CO₃ solvent with low temperature vacuum stripping could be potentially advanced by lowering vacuum pressure, improving strategies for increasing rich CTB conversion (e.g., advanced packing column and optimized L/G ratio), and decreasing absorption temperature.