Synthesis of Perfluoroalkyl End-Functionalized Poly(3-hexylthiophene) and the Effect of Fluorinated End Groups on Solar Cell Performance

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• 作者：Zhenghao Mao ; Kiarash Vakhshouri ; Cherno Jaye ; Daniel A. Fischer ; Roshan Fernando ; Dean M. DeLongchamp ; Enrique D. Gomez ; Genevi猫ve Sauv茅
• 刊名：Macromolecules
• 出版年：2013
• 出版时间：January 8, 2013
• 年：2013
• 卷：46
• 期：1
• 页码：103-112
• 全文大小：685K
• 年卷期：v.46,no.1(January 8, 2013)
• ISSN：1520-5835

文摘

A series of well-defined perfluoroalkyl end-functionalized poly(3-hexylthiophenes) (P3HT) were synthesized by Stille coupling of stannylated 2-perfluoralkylthiophene with the bromine end of P3HT. The length of the perfluoroalkyl end group was varied from 鈭扖₄F₁₃ to 鈭扖₈F₁₇. These polymers were fully characterized and tested in bulk heterojunction solar cells with phenyl-C₆₁-butyric acid methyl ester (PCBM) as the acceptor. Performance of the solar cells was highest for the unmodified P3HT and decreased as the length of the perfluoroalkyl end increased. The most affected device parameters were the short-circuit current density (J_sc) and series resistance, pointing to lower charge carrier mobility and poor morphology as the cause for the lower performance. While the morphology of blends did not significantly change with perfluoroalkyl end modification, analysis of blended films by energy-filtered transmission electron microscopy (EF-TEM) revealed wider P3HT domains, consistent with the perfluorinated end groups segregating to the edge or exterior of P3HT domains, causing two domains to join. This study demonstrates that the perfluoroalkyl end group can be detrimental to polymer solar cell device performance, and further work toward understanding the interface between the donor and acceptor phases is required to fully understand this effect.