Tailoring the Pore Size and Functionality of UiO-Type Metal鈥揙rganic Frameworks for Optimal Nerve Agent Destruction
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- 作者：Gregory W. Peterson ; Su-Young Moon ; George W. Wagner ; Morgan G. Hall ; Jared B. DeCoste ; Joseph T. Hupp ; Omar K. Farha
- 刊名：Inorganic Chemistry
- 出版年：2015
- 出版时间：October 19, 2015
- 年：2015
- 卷：54
- 期：20
- 页码：9684-9686
- 全文大小：267K
- ISSN：1520-510X
文摘
Evaluation of UiO-66 and UiO-67 metal鈥搊rganic framework derivatives as catalysts for the degradation of soman, a chemical warfare agent, showed the importance of both the linker size and functionality. The best catalysts yielded half-lives of less than 1 min. Further testing with a nerve agent simulant established that different rate-assessment techniques yield similar values for degradation half-lives.