Synthesis and Molecular Structures of BINOL Complexes: An STM Investigation of 2D Self-Assembly

详细信息    查看全文

• 作者：Xianghua Zeng ; Shaoqing Chang ; Ke Deng ; Junyong Zhang ; Hongbin Sun ; Qingdao Zeng ; Jingli Xie
• 刊名：Crystal Growth & Design
• 出版年：2015
• 出版时间：July 1, 2015
• 年：2015
• 卷：15
• 期：7
• 页码：3096-3100
• 全文大小：466K
• ISSN：1528-7505

文摘

Three new (R)-BINOL complexes have been prepared. 2D self-assembly has been observed in the system consisting of crystalline (R)-BINOL derivatives (guest) and 1,3,5-tris(10-carboxydecyloxy)-benzene (host) by means of the scanning tunneling microscopy (STM) technique. Density functional theory (DFT) calculations help to reveal the assembly on the HOPG surface.