Stereocontrolled Total Syntheses of (±)-Fawcettimine, (±)-Lycoflexine, and (±)-Lycoflexine N-Oxide

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• 作者：Ke Xu ; Bin Cheng ; Yun Li ; Tingting Xu ; Cunming Yu ; Jun Zhang ; Zhiqiang Ma ; Hongbin Zhai
• 刊名：Organic Letters
• 出版年：2014
• 出版时间：January 3, 2014
• 年：2014
• 卷：16
• 期：1
• 页码：196-199
• 全文大小：324K
• ISSN：1523-7052

文摘

New stereocontrolled total syntheses of (卤)-fawcettimine, (卤)-lycoflexine, and (卤)-lycoflexine N-oxide have been accomplished. The highlights include a one-pot annulation to construct the enedione and a microwave-promoted Diels鈥揂lder reaction.