Preparation of Peapod Polymer via the Supramolecular Chain Formation by Tris(spiroborate) Twin Bowl

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• 作者：Hiroshi DanjoToshi Nakagawa ; Akio Morii ; Yusuke Muraki ; Koichi Sudoh
• 刊名：ACS Macro Letters
• 出版年：2017
• 出版时间：January 17, 2017
• 年：2017
• 卷：6
• 期：1
• 页码：62-65
• 全文大小：348K
• ISSN：2161-1653

文摘

Successive guest-containing tubular polymer was prepared by the olefin metathesis polymerization of tris(spiroborate) twin bowl after the formation of supramolecular polymer. The cationic iridium(III) complexes were topologically fixed inside the polymer to form a peapod-like structure. The polymer was evaluated by SEC, ICP-AES, and DLS analyses, and string-like structures were found in the AFM observation of the peapod polymer.