Identification of Surface Reactivity Descriptor for Transition Metal Oxides in Oxygen Evolution Reaction

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• 作者：Hua Bing Tao ; Liwen Fang ; Jiazang Chen ; Hong Bin Yang ; Jiajian Gao ; Jianwei Miao ; Shengli Chen ; Bin Liu
• 刊名：Journal of the American Chemical Society
• 出版年：2016
• 出版时间：August 10, 2016
• 年：2016
• 卷：138
• 期：31
• 页码：9978-9985
• 全文大小：563K
• 年卷期：0
• ISSN：1520-5126

文摘

A number of important reactions such as the oxygen evolution reaction (OER) are catalyzed by transition metal oxides (TMOs), the surface reactivity of which is rather elusive. Therefore, rationally tailoring adsorption energy of intermediates on TMOs to achieve desirable catalytic performance still remains a great challenge. Here we show the identification of a general and tunable surface structure, coordinatively unsaturated metal cation (M_CUS), as a good surface reactivity descriptor for TMOs in OER. Surface reactivity of a given TMO increases monotonically with the density of M_CUS, and thus the increase in M_CUS improves the catalytic activity for weak-binding TMOs but impairs that for strong-binding ones. The electronic origin of the surface reactivity can be well explained by a new model proposed in this work, wherein the energy of the highest-occupied d-states relative to the Fermi level determines the intermediates’ bonding strength by affecting the filling of the antibonding states. Our model for the first time well describes the reactivity trends among TMOs, and would initiate viable design principles for, but not limited to, OER catalysts.