Application of Iron-Containing Magnetic Ionic Liquids in Extraction Process of Coal Direct Liquefaction Residues

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• 作者：Jieli Wang ; Hongwei Yao ; Yi Nie ; Lu Bai ; Xiangping Zhang ; Jianwei Li
• 刊名：Industrial & Engineering Chemistry Research
• 出版年：2012
• 出版时间：March 7, 2012
• 年：2012
• 卷：51
• 期：9
• 页码：3776-3782
• 全文大小：293K
• 年卷期：v.51,no.9(March 7, 2012)
• ISSN：1520-5045

文摘

Three kinds of iron-containing magnetic ionic liquids (ILs), including imidazole-based, pyridine-based, and pyrrolidine-based ILs, were synthesized respectively, and were used to dissolve coal direct liquefaction residues (CDLR) to obtain asphaltene fractions under the conditions of given time, temperature, and mass ratio of ILs to CDLR. The extracts from CDLR were characterized by ultimate analysis, proximate analysis, FT-IR, and ¹³C NMR. The results show that physicochemical properties of the extracts obtained with different magnetic ILs consisting of different cationic rings are different, and pyridine-based magnetic IL is an effective extractant to extract asphaltenes from CDLR among the three magnetic ILs. The extracts might be good precursors for preparing high-value-added carbon materials because of their higher carbon content, lower H/C, and ash content.