Cocrystallization of Mononuclear and Trinuclear Metallacycle Molecules from an Aqueous Mixed-Ligand Copper(II) Solution

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• 作者：Hanan El Bakkali ; Duane Choquesillo-Lazarte ; Alicia Dom铆nguez-Mart铆n ; M. Inmaculada P茅rez-Toro ; L. Lezama ; Josefa M. Gonz谩lez-P茅rez ; Alfonso Casti帽eiras ; Juan Nicl贸s-Guti茅rrez
• 刊名：Crystal Growth & Design
• 出版年：2014
• 出版时间：March 5, 2014
• 年：2014
• 卷：14
• 期：3
• 页码：889-892
• 全文大小：289K
• 年卷期：v.14,no.3(March 5, 2014)
• ISSN：1528-7505

文摘

The compound [Cu(渭₂-NamIDA)(2,4-dapyd)]₃路3[Cu(NamIDA)(2,4-dapyd)(H₂O)]路21H₂O (NamIDA = N-(1-naphtylmethyl)iminodiacetate(2-) and 2,4-dapyd = 2,4-diaminopyrimidine) is a spontaneous cocrystal with mononuclear and trinuclear metallacycle complex molecules, where extensive intermolecular H bonds play a key role.