Ruthenium(III)-Catalyzed β-Alkylation of Secondary Alcohols with Primary Alcohols

详细信息    查看全文

• 作者：Qingfu Wang ; Kaikai Wu ; Zhengkun Yu
• 刊名：Organometallics
• 出版年：2016
• 出版时间：May 9, 2016
• 年：2016
• 卷：35
• 期：9
• 页码：1251-1256
• 全文大小：380K
• 年卷期：0
• ISSN：1520-6041

文摘

A Ru(III)-NNN complex bearing a pyridyl-supported pyrazolyl-imidazolyl ligand was synthesized and utilized as the catalyst for the direct β-alkylation of secondary alcohols with primary alcohols. β-Alkylated secondary alcohols were obtained in moderate to high yields with water formed as the byproduct through a hydrogen borrowing pathway. The present protocol provides a concise atom-economical and environmentally benign method for C–C bond formation.