Elaboration of a Highly Porous RuII,II Analogue of HKUST-1

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• 作者：Wenhua Zhang ; Kerstin Freitag ; Suttipong Wannapaiboon ; Christian Schneider ; Konstantin Epp ; Gregor Kieslich ; Roland A. Fischer
• 刊名：Inorganic Chemistry
• 出版年：2016
• 出版时间：December 19, 2016
• 年：2016
• 卷：55
• 期：24
• 页码：12492-12495
• 全文大小：273K
• ISSN：1520-510X

文摘

When the dinuclear Ru^II,II precursor [Ru₂(OOCCH₃)₄] is employed under redox-inert conditions, a Ru^II,II analogue of HKUST-1 was successfully prepared and characterized as a phase-pure microcrystalline powder. X-ray absorption near-edge spectroscopy confirms the oxidation state of the Ru centers of the paddle-wheel nodes in the framework. The porosity of 1371 m²/mmol of Ru^II,II-HKUST-1 exceeds that of the parent compound HKUST1 (1049 m²/ mmol).