Controllable Fabrication of Coordination Polymer Particles (CPPs): A Bridge between Versatile Organic Building Blocks and Porous Copper-Based Inorganic Materials

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• 作者：Kuaibing Wang ; Zhirong Geng ; Mingbo Zheng ; Luyao Ma ; Xiaoyan Ma ; Zhilin Wang
• 刊名：Crystal Growth & Design
• 出版年：2012
• 出版时间：November 7, 2012
• 年：2012
• 卷：12
• 期：11
• 页码：5606-5614
• 全文大小：697K
• 年卷期：v.12,no.11(November 7, 2012)
• ISSN：1528-7505

文摘

Hierarchically micro-/nanostructured coordination polymer [Cu(2,5-PDC)H₂O]_n architectures with tunable morphologies have been successfully prepared by rationally adjusting the preparation parameters, such as the reactant concentration, solvent, surfactant, and reaction temperature. Using simple calcinations of chosen shaped [Cu(2,5-PDC)H₂O]_n architectures, we can obtain several porous copper-based inorganic motifs, which show potential applications for the antibacterial field and lithium ion batteries. Therein, CuO-1 can kill the Gram-positive bacteria Bacillus subtilis and Staphylococcus aureus better than other materials. The value for initial discharge capacity of CuO-3 (1160 mAh g^鈥?) is higher than the theoretical capacity (674 mAh g^鈥?) and most copper oxide materials. Besides, Cu/C composites also show intense application in the antibacterial and Li-ions uptake-release field, which will provide a widely used method to prepare the nanosystem of carbon-coating or carbon-compositing materials by simple calcinations of shaped precursor coordination polymer particles used under the proper temperature.