Cu(II)-Mediated Methylthiolation of Aryl C−H Bonds with DMSO

详细信息    查看全文

• 作者：Lingling Chu ; Xuyi Yue ; Feng-Ling Qing
• 刊名：Organic Letters
• 出版年：2010
• 出版时间：April 2, 2010
• 年：2010
• 卷：12
• 期：7
• 页码：1644-1647
• 全文大小：243K
• 年卷期：v.12,no.7(April 2, 2010)
• ISSN：1523-7052

文摘

An unprecedented Cu(II)-mediated methylthiolation of aryl C−H bonds under oxidative conditions that employs the widely available DMSO as the methylthiolation reagent is described. Various functional groups in the substrates were tolerated, and ethylthiolation was also successfully achieved directly from diethyl sulfoxide under the same reaction conditions.