Aggregation Behavior of Imidazolium-Based Surface-Active Ionic Liquids with Photoresponsive Cinnamate Counterions in the Aqueous Solution

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• 作者：Yanhui Bi ; Liuchen Zhao ; Qiongzheng Hu ; Yan鈥檃n Gao ; Li Yu
• 刊名：Langmuir
• 出版年：2015
• 出版时间：November 24, 2015
• 年：2015
• 卷：31
• 期：46
• 页码：12597-12608
• 全文大小：526K
• ISSN：1520-5827

文摘

Two imidazolium-based surface active ionic liquids (SAILs) with photoresponsive cinnamate aromatic counterions, viz. 1-dodecyl-3-methylimidazolium cinnamate ([C₁₂mim][CA]) and 1-dodecyl-3-methylimidazolium para-hydroxy-cinnamate ([C₁₂mim][PCA]), were newly synthesized, and their self-assembly behaviors in aqueous solutions were systematically explored. Results of surface tension and conductivity measurements show that both [C₁₂mim][CA] and [C₁₂mim][PCA] display a superior surface activity in aqueous solutions compared to the common imidazolium-based SAIL, 1-dodecyl-3-methylimidazolium bromide (C₁₂mimBr), which implies the incorporation of cinnamate aromatic counterions can promote the micellar formation. Furthermore, [C₁₂mim][CA] shows higher surface activity due to the higher hydrophobicity of its counterion in comparison to [C₁₂mim][PCA] that has a hydroxyl group. Both hexagonal liquid-crystalline phase (H₁) and cubic liquid-crystalline phase (V₂) were constructed in the [C₁₂mim][CA] aqueous solutions. In contrast, the [C₁₂mim][PCA]/H₂O system only exhibits a single hexagonal liquid-crystalline phase (H₁) in a broad concentration region. These lyotropic liquid crystal (LLC) phases were comprehensively characterized by polarized optical microscopy (POM), small-angle X-ray scattering (SAXS), and rheometer. Investigation on the temperature-dependent self-assembly nanostructures demonstrates that the higher temperature leads to a looser arrangement. Under UV irradiation, trans鈥揷is photoisomerization of the phenylalkene group results in inferior surface activity of the prepared SAILs in aqueous solution with higher cmc values. Moreover, UV light irradiation induces obvious change of the structural parameters without altering the LLC phases. This work is expected to enrich the investigations of phase behaviors formed in SAILs systems and receive particular attention due to their unique properties and potential applications in drug delivery, biochemistry, materials science, etc.