Efficient Base-Free Hydrogenation of Amides to Alcohols and Amines Catalyzed by Well-Defined Pincer Imidazolyl–Ruthenium Complexes

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• 作者：Jose R. Cabrero-Antonino ; Elisabetta Alberico ; Hans-Joachim Drexler ; Wolfgang Baumann ; Kathrin Junge ; Henrik Junge ; Matthias Beller
• 刊名：ACS Catalysis
• 出版年：2016
• 出版时间：January 4, 2016
• 年：2016
• 卷：6
• 期：1
• 页码：47-54
• 全文大小：473K
• ISSN：2155-5435

文摘

Novel homogeneous ruthenium catalysts bearing an imidazolylaminophosphino pincer ligand have been synthesized. The active catalyst allows for the hydrogenation of a range of amides under base-free conditions to afford the corresponding alcohols and amines in high yields.