Bottleable (Amino)(Carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes

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• 作者：Janell K. Mahoney ; David Martin ; Curtis E. Moore ; Arnold L. Rheingold ; Guy Bertrand
• 刊名：Journal of the American Chemical Society
• 出版年：2013
• 出版时间：December 18, 2013
• 年：2013
• 卷：135
• 期：50
• 页码：18766-18769
• 全文大小：242K
• 年卷期：v.135,no.50(December 18, 2013)
• ISSN：1520-5126

文摘

Monomeric (amino)(carboxy) radicals were synthesized in two steps: the addition of a stable cyclic (alkyl)(amino) carbene to an acyl chloride, followed by a one-electron reduction. Their stability toward dimerization also allows for the synthesis of related bi- and triradicals.