Synergic Nitrogen Source Route to Inorganic Fullerene-like Boron Nitride with Vessel, Hollow Sphere, Onion, and Peanut Nanostructures
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- 作者：Fen Xu ; Yi Xie ; Xu Zhang ; Shuyuan Zhang ; Xianming Liu ; and Xiaobo Tian
- 刊名：Inorganic Chemistry
- 出版年：2004
- 出版时间：January 26, 2004
- 年：2004
- 卷：43
- 期：2
- 页码：822 - 829
- 全文大小：348K
- 年卷期：v.43,no.2(January 26, 2004)
- ISSN：1520-510X
文摘
In this paper we describe the large-scale synthesis of inorganic fullerene-like (IF-like) hexagonal boron nitride withvessel, hollow sphere, peanut, and onion structures by reacting BBr3 with the synergic nitrogen sources NaNH2and NH4Cl at 400-450 
C for 6-12 h. The composition of products could be confirmed to be pure boron nitridewith hexagonal structures by the XRD patterns and FT-IR, XPS, and EDXA spectra. The representative HRTEMimages clearly reveal the layerlike features of the products. Here, the peanut-like structure of the IF-like BN isreported for the first time, and added to the list as one kind of new morphology of BN nanomaterials. The similarityin the structure between h-BN and graphite is responsible for the formation of IF-like BN with nanostructures ofvessels, hollow spheres, peanuts, and onions.
C for 6-12 h. The composition of products could be confirmed to be pure boron nitridewith hexagonal structures by the XRD patterns and FT-IR, XPS, and EDXA spectra. The representative HRTEMimages clearly reveal the layerlike features of the products. Here, the peanut-like structure of the IF-like BN isreported for the first time, and added to the list as one kind of new morphology of BN nanomaterials. The similarityin the structure between h-BN and graphite is responsible for the formation of IF-like BN with nanostructures ofvessels, hollow spheres, peanuts, and onions.