Syntheses, Structures, and Properties of Copper(II) Complexes of Bis(2-pyridylmethyl) Derivatives of o-, m-, and p-Phenylenediamine and Aniline

详细信息    查看全文

• 作者：Sabrina Turba ; Olaf Walter ; Siegfried Schindler ; Lars Preuss Nielsen ; Alan Hazell ; Christine J. McKenzie ; Francesc Lloret ; Joan Cano ; Miguel Julve
• 刊名：Inorganic Chemistry
• 出版年：2008
• 出版时间：October 20, 2008
• 年：2008
• 卷：47
• 期：20
• 页码：9612-9623
• 全文大小：351K
• 年卷期：v.47,no.20(October 20, 2008)
• ISSN：1520-510X

文摘

Copper(II) complexes of the ligand 1,n-bis[bis(2-pyridylmethyl)amino]benzene with n = 2−4 (1,n-tpbd) and its mononuclear derivative bis(2-pyridylmethyl)aniline (phbpa) were synthesized and structurally characterized. Magnetic measurements and DFT calculations were performed on [CuCl₂(phbpa)], [Cu₂Cl₄(1,3-tpbd)], [(Cu₂Cl₂(ClO₄)(1,3-tpbd))Cl(Cu₂Cl₂(OH₂)(1,3-tpbd))](ClO₄)₂, and [Cu₂(OH₂)₂(S₂O₆)(1,3-tpbd)]S₂O₆, and the exchange-polarization mechanism was successfully demonstrated.