Solid–Liquid Equilibria in the Binary Systems of Saturated Fatty Acids or Triglycerides (C12 to C18) + Hexadecane

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• 作者：Kazuko Yui ; Yasuhiro Itsukaichi ; Takuro Kobayashi ; Tomoya Tsuji ; Keisuke Fukui ; Kouji Maeda ; Hidetoshi Kuramochi
• 刊名：Journal of Chemical & Engineering Data
• 出版年：2017
• 出版时间：January 12, 2017
• 年：2017
• 卷：62
• 期：1
• 页码：35-43
• 全文大小：381K
• ISSN：1520-5134

文摘

Solid–liquid equilibria (SLE) for the binary systems of C12–C18 saturated fatty acids or their triglycerides + hexadecane (systems of dodecanoic acid (lauric acid), tetradecanoic acid (myristic acid), hexadecanoic acid (palmitic acic), octadecanoic acid (stearic acid), 1,2,3-propanetriyl tridodecanoate (trilaurin), 1,2,3-propanetriyl tritetradecanoate (trimyristin), 1,2,3-propanetriyl trihexadecanoate (tripalmitin), or 1,2,3-propanetriyltrioctadecanoate (tristearin), + hexadecane) were measured in the hexadecane fractions of 0 to 1 and temperatures from (273.2 to 353.2) K, using differential scanning calorimetry. These systems were selected as model systems for blending oily content extracted from restaurant trap grease with fossil fuel oils. The obtained liquidus curves were discussed in terms of the effects of carbon chain length, chemical form, and variation in the liquid component. In addition, the experimental liquidus curves were compared with predictions based on ideal solution approximation and on the LLE-UNIFAC and Dortmund-UNIFAC models. The triglyceride and hexadecane binary systems were close to the ideal solution, while the fatty acid–hexadecane binary systems were not. The Dortmund-UNIFAC model successfully predicted all liquidus curves of the nonideal, fatty acid–hexadecane systems.