Synthesis of (Z)-α-Trifluoromethyl Alkenyl Triflate: A Scaffold for Diverse Trifluoromethylated Species

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• 作者：Yilong Zhao ; Yuhan Zhou ; Juan Liu ; Dongmei Yang ; Liang Tao ; Yang Liu ; Xiaoliang Dong ; Jianhui Liu ; Jingping Qu
• 刊名：Journal of Organic Chemistry
• 出版年：2016
• 出版时间：June 3, 2016
• 年：2016
• 卷：81
• 期：11
• 页码：4797-4806
• 全文大小：602K
• 年卷期：0
• ISSN：1520-6904

文摘

An efficient method for the synthesis of (Z)-selective α-trifluoromethyl alkenyl triflates is described. As an important fluorinated building block, it is utilized successfully for the synthesis of various trifluoromethyl derivatives such as diarylethylenes, enynes, alkynes, and benzofurans.