Free-Radical Carbo-alkenylation of Enamides and Ene-carbamates

详细信息    查看全文

• 作者：Cl茅ment Poittevin ; Virginie Liautard ; Redouane Beniazza ; Fr茅d茅ric Robert ; Yannick Landais
• 刊名：Organic Letters
• 出版年：2013
• 出版时间：June 7, 2013
• 年：2013
• 卷：15
• 期：11
• 页码：2814-2817
• 全文大小：310K
• 年卷期：v.15,no.11(June 7, 2013)
• ISSN：1523-7052

文摘

The addition of xanthates and vinyldisulfones across the double bond of enamides and ene-carbamates provides access to the corresponding three-component adducts in good to excellent yields with a high level of diastereocontrol in cyclic systems. This strategy illustrates a complementary reactivity for these versatile olefins and extends their scope of application.