Liquid phase hydroxylation of benzene to phenol over vanadyl acetylacetonate supported on amine functionalized SBA-15

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• 作者：Yaohui Bao ; Hong Jiang ; Weihong Xing…
• 关键词：Vanadyl acetylacetonate ; Amine functionalized SBA ; 15 ; (3 ; Aminopropyl)triethoxysilane ; Benzene hydroxylation ; Molecular oxygen
• 刊名：Reaction Kinetics, Mechanisms and Catalysis
• 出版年：2015
• 出版时间：December 2015
• 年：2015
• 卷：116
• 期：2
• 页码：535-547
• 全文大小：702 KB
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• 作者单位：Yaohui Bao (1)
  Hong Jiang (1)
  Weihong Xing (1)
  Rizhi Chen (1)
  Yiqun Fan (1)
  
  1. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing, 210009, Jiangsu, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Industrial Chemistry and Chemical Engineering
  Physical Chemistry
  
• 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
• ISSN：1878-5204

文摘

An efficient catalyst for the direct hydroxylation of benzene to phenol with oxygen as the oxidant was developed by immobilizing the homogeneous vanadyl(IV) acetylacetonate (VO(acac)₂) on SBA-15 in which the support surface was functionalized by (3-aminopropyl)triethoxysilane. The as-prepared catalyst was characterized by various techniques including field-emission scanning electron microscopy, X-ray diffraction, nitrogen adsorption and desorption, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. The results show that the homogeneous vanadium species can be successfully immobilized on the amine functionalized SBA-15 and exhibits better catalytic performance in the hydroxylation of benzene with oxygen compared to other catalysts reported in the literature. The phenol yield significantly depends on the reaction conditions. Under the optimized reaction conditions, the phenol yield can reach 13.3 %, and the as-fabricated V/NH₂-SBA-15 shows better stability against leaching owning to strong interaction between vanadium atoms and amine group as compared to the V/SBA-15 sample. Keywords Vanadyl acetylacetonate Amine functionalized SBA-15 (3-Aminopropyl)triethoxysilane Benzene hydroxylation Molecular oxygen