Microwave absorption behavior of a polyaniline magnetic composite in the X-band

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• 作者：J.C. Aphesteguy^a ; A. Damiani^b ; D. DiGiovanni^b ; S.E. Jacobo^a ; ^{sjacobo@fi.uba.ar}
• 关键词：Magnetic Nanocomposites ; Conducting polyaniline ; Microwave absorption
• 刊名：Physica B
• 出版年：2012
• 期刊代码：53_09214526
• 类别：ph
• 出版时间：15 August, 2012
• 卷：407
• 期：16
• 页码：3168-3171
• 文件大小：569 K

摘要

The development of nanosized materials is a subject of considerable interest both for understanding of the fundamental properties of magnetic materials for new technological applications. Polyaniline, composites Fe₃O₄/(PANI) with conducting, magnetic and electromagnetic properties with different amounts of Fe₃O₄ were successfully prepared. The samples were structurally characterized by scanning electron microscopy (SEM), X-ray diffraction and transmission electron microscopy (TEM) and magnetically, with a superconducting quantum interference device (SQUID) magnetometer. In order to explore microwave-absorbing properties in X-band, the composite nanoparticles were mixed with an epoxy resin to be converted into a microwave-absorbing composite. Microwave behavior with different Fe₃O₄/(PANI)-epoxy resin ratio was studied using a microwave vector network analyzer (VNA) in the range 7.5 to 13 GHz. For a constant thickness of 1.5 mm, absorption increases with the magnetite contents in the composites and in the oriented samples by the application of a magnetic field.