Occurrence and fate of polycyclic aromatic hydrocarbons in the coastal surface microlayer
- 作者：Carlos Guitart ; Nuria Garcí ; a-Flor ; Josep M. Bayona ; Joan Albaigé ; s
- 关键词：Sea surface microlayer ; PAHs ; Sources ; Surface enrichment ; Coastal environment ; Mediterranean Sea
- 刊名：Marine Pollution Bulletin
- 出版年：2007
- 期刊代码：76_0025326x
- 类别：abs
- 出版时间：February 2007
- 卷：54
- 期：2
- 页码：186-194
- 文件大小：466 K
摘要
Polycyclic aromatic hydrocarbons (PAHs) were measured in the coastal sea surface microlayer (SML), the sub-surface waters (SSW) and the overlying atmosphere in order to investigate the influence of the SML on contaminant enrichment and air–sea exchange. Samples were collected at two contrasting locations of the NW Mediterranean, one urban influenced (off Barcelona, Spain) and another comparatively clean (off Banyuls-sur-Mer, France). Statistical data analysis confirmed the accumulation of PAHs in the SML with respect to the SSW (20.3 ± 9.1 vs. 13.1 ± 10.0 ng L<sup>−1sup> in the dissolved phase; 709 ± 207 vs. 158 ± 111 ng g<sup>−1sup> in the particulate phase). This accumulation was higher at the contaminated location (Barcelona station) compared with the more pristine one, with PAH enrichments 1.5 and 4.5 times higher for the dissolved and particulate phases, respectively, indicating that the enrichment of PAHs in the SML is dominated by particle transport processes.