Fast redox switching into the conducting state, related to single mono-cationic/polaronic charge carriers only in cation exchanger type conducting polymers

详细信息	查看全文 | 推荐本文 |

• 作者：Pé ; ter S. Tó ; th ; Emese Peintler-Krivá ; n ; Csaba Visy ; ^{visy@chem.u-szeged.hu}
• 关键词：Conducting polymers ; UV&ndash ; vis-NIR ; a. c. conductance ; EQCN ; Redox mechanism
• 刊名：Electrochemistry Communications
• 出版年：2012
• 期刊代码：29_13882481
• 类别：ch
• 出版时间：2012
• 卷：18
• 期：Complete
• 页码：16-19
• 文件大小：564 K

摘要

Simultaneously performed in situ conductance and spectro-electrochemical measurements鈥攃ompleted by EQCN鈥攑roved that fast redox switching can only be expected in cation exchanger type polymers, where the conductance develops promptly with the formation of mono-cationic/polaronic charge carriers鈥攄ue assumingly to the presence of the charge compensating anions in favorable distribution.