Characterization of single phase copper selenide nanoparticles and their growth mechanism

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• 作者：D. Patidar ; ^{dinupatidar@gmail.com} ; N.S. Saxena
• 关键词：A1. Electron diffraction ; A3. Growth mechanism ; B1. Copper selenide ; B2. Absorption spectrum
• 刊名：Journal of Crystal Growth
• 出版年：2012
• 期刊代码：49_00220248
• 类别：ch
• 出版时间：15 March, 2012
• 卷：343
• 期：1
• 页码：68-72
• 文件大小：501 K

摘要

The high quality Cu₃Se₂ phase of copper selenide nanoparticles was synthesized through the solution-phase chemical reaction between copper and selenium. In this synthesis process, hydrazine hydrate acts as reducing agent whereas ethylene glycol controls the nucleation and growth of particles. An effort has been made to explain the growth mechanism to form copper selenide nanoparticles through the coordination of selenium to the Cu²⁺ complexes with OH groups of ethylene glycol. Result indicates the formation of Cu₃Se₂ single phase nanoparticles. The particles with the average particle size 25 nm are spherical in shape having tetragonal structure. The particles are well crystallized having 94%degree of crystallinity. An effort has also been made to determine the energy band gap of copper selenide nanoparticles through the absorption spectra.