Structural overview of technetium compounds (2000–2004)

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• 作者：Giuliano Bandoli ; Francesco Tisato ; Alessandro Dolmella and Stefania Agostini
• 关键词：[ ; Tc(CO)₃] ; ⁺ complexes ; Tc(III) complexes ; Nitrido-Tc(V) complexes ; Oxo-Tc(V) complexes ; X-ray structures
• 刊名：Coordination Chemistry Reviews
• 出版年：2006
• 期刊代码：27_00108545
• 类别：ch
• 出版时间：February 2006
• 卷：250
• 期：3-4
• 页码：561-573
• 文件大小：498 K

摘要

This paper provides an overview of the about 80 crystal structures of technetium complexes described in the past 5 years and exhibiting some peculiar structural features. In almost 90%of the compounds, technetium shows an odd oxidation number, and by a large majority the revised complexes are mononuclear and neutral. The review especially focuses on nitrido-Tc(V), oxo-Tc(V) and fac-[Tc(CO)₃]⁺ complexes, which cover approximately one-half of the X-ray structural reports.