Adhesion and micromechanical deformation processes in PLA/CaSOb>4b> composites

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• 作者：Balá ; zs Imre^a ; ^b ; Gergely Keledi^a ; ^b ; Ká ; roly Renner^a ; ^b ; Já ; nos Mó ; czó ; ^a ; ^b ; Marius Murariu^c ; Philippe Dubois^c ; Bé ; la Puká ; nszky^a ; ^b ; ^{bpukanszky@mail.bme.hu}
• 关键词：PLA/CaSO4 bio-composites ; Interfacial adhesion ; Debonding ; Surface modification
• 刊名：Carbohydrate Polymers
• 出版年：2012
• 期刊代码：14_01448617
• 类别：ch
• 出版时间：1 July, 2012
• 卷：89
• 期：3
• 页码：759-767
• 文件大小：1369 K

摘要

PLA/CaSOb>4b> composites were prepared from uncoated and stearic acid coated filler particles in a wide composition range. The strength of interfacial adhesion was estimated quantitatively with three independent methods. Structure was characterized by DSC, XRD and SEM measurements, while mechanical properties by tensile and instrumented impact tests. The results proved that adhesion is twice as strong in composites prepared with the uncoated particles than in those containing the coated filler. Coating changes also local deformation processes around the particles. Although debonding is the dominating micromechanical deformation process in all composites, local plastic deformation is larger around coated particles. The extent of this deformation depends very much also on the local distribution of particles. The final properties and performance of the composites depend unambiguously on the micromechanical deformation processes occurring during loading, on debonding and the subsequent plastic deformation. Stearic acid used for the coating of the filler seems to dissolve in the polymer and locally change its properties.