A novel incorporating style of polyaniline/TiO₂ composites as effective visible photocatalysts

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• 作者：Liuan Gu ; Jingyu Wang ; ^{jingyu.wang@163.com} ; Rong Qi ; Xiaoyu Wang ; Ping Xu ; Xijiang Han ; ^{hanxj63@yahoo.com.cn}
• 关键词：Polyaniline/TiO2 ; Incorporating style ; Hydrothermal synthesis ; Visible photoactivity
• 刊名：Journal of Molecular Catalysis A ; Chemical
• 出版年：2012
• 期刊代码：57_13811169
• 类别：ch
• 出版时间：May, 2012
• 卷：357
• 期：Complete
• 页码：19-25
• 文件大小：958 K

摘要

Herein we obtain a novel incorporating style of polyaniline (PANI)/TiO₂ composites (Ns) via a designed two-step route. In comparison with conventional incorporating style (Cs), one-dimensional (1D) PANI is introduced in the step of TiO₂ crystal growth instead of after crystallization. During the hydrothermal process, 1D PANI can act as an effective template to stabilize TiO₂ particles at nanoscale through interfacial chemical bonds. In this way, the transition of some newly formed anatase crystals to rutile phase is partly suppressed. Also, the as-prepared composites show obvious light response in a wide range of 230-900 nm due to the sensitizing effect of PANI. Ns exhibit the improved visible photocatalytic property with scarce decrease of UV photoactivity. Overall, this work would provide new insights into the fabrication of conducting polymer/semiconductor composites with desired nanostructure as high performance photocatalysts and would facilitate their applications in environmental purification and solar energy conversion.