New octa- and dodecametallic mixed-valent Mn rods
- 作者：Maria Manoli ; Constantinos J. Milios ; Abhudaya Mishra ; George Christou ; Euan K. Brechin
- 关键词：Magnetism ; Single-molecule magnets ; Mn complexes ; Tripodal alcohols
- 刊名：Polyhedron
- 出版年：2007
- 期刊代码：87_02775387
- 类别：ch
- 出版时间：15 June 2007
- 卷：26
- 期：9-11
- 页码：1923-1926
- 文件大小：360 K
摘要
The combination of MnBr2 · 4H2O with tripodal alcohols results in the formation of new octa- and dodecametallic and clusters. Their structures describe ‘one-dimensional’ rod-like arrays of six and ten edge-sharing triangles, respectively. Both complexes display S ≈ 0 spin ground states.
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