Laboratory desalination experiments with some algal toxins

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• 作者：Maurice V. Laycock^a ; ^{mlaycock@eastlink.ca} ; Donald M. Anderson^b ; Jerome Naar^c ; Allan Goodman^c ; Dorothy J. Easy^a ; Mary Anne Donovan^a ; Aifeng Li^d ; ^e ; Michael A. Quilliam^d ; Ebrahim Al Jamali^f ; Rashid Alshihi^f
• 关键词：LC ; Liquid chromatography ; MS ; Mass spectrometry ; ELISA ; Enzyme-linked immunosorbent assay ; STX ; Saxitoxin ; PSP ; Paralytic shellfish poisoning ; ASP ; Amnesic shellfish poisoning ; DSP ; Diarrhetic shellfish poisoning ; NSP ; Neurotoxic shellfish poisoning ; RO
• 刊名：Desalination
• 出版年：2012
• 期刊代码：24_00119164
• 类别：ce
• 出版时间：1 May, 2012
• 卷：293
• 期：Complete
• 页码：1-6
• 文件大小：398 K

摘要

Over the last several decades, countries throughout the world have experienced an escalating and worrisome trend in the incidence of harmful algal blooms (HABs). A concern is that highly potent algal toxins might be retained in the treated water, posing a threat to human health. Seawater contaminated with saxitoxins, domoic acid, okadaic acid, and brevetoxins was desalinated using small (< 100 mL capacity) reverse osmosis and distillation equipment. Analyses of desalinated water samples indicated efficient removal of the four toxins to greater than 99%, except brevetoxins for which some carry-over was observed during distillation. Hypochlorite concentrations of 4 ppm or higher were sufficient to react with all of the saxitoxins, domoic acid and okadaic acid in the samples that contained initial toxin concentrations up to 1250 ng mL^鈭?#xA0;1. Brevetoxins appeared to be unaffected in experiments in which the toxins were exposed to up to 30 ppm hypochlorite in seawater at 35 掳C for 60 min. These results and their implications in terms of desalination plant design and operation are discussed.