Kinetics and mechanism of the pyridine-catalyzed reaction of phenylselenenyl halides and some unsaturated alcohols

详细信息	查看全文 | 推荐本文 |

• 作者：Zorica M. Bugarč ; i&#x107 ; Biljana V. Petrovi&#x107 ; Marina D. Rvovi&#x107
• 关键词：Alcohol ; Cyclization ; Kinetics ; Mechanism ; Pyridine
• 刊名：Journal of Molecular Catalysis A ; Chemical
• 出版年：2008
• 期刊代码：57_13811169
• 类别：ch
• 出版时间：15 May 2008
• 卷：287
• 期：1-2
• 页码：171-175
• 文件大小：603 K

摘要

The kinetics and mechanism of the reaction of phenylselenenyl halides (PhSeX, X = Cl, Br) and some primary unsaturated alcohols (pent-4-en-1-ol and hex-5-en-1-ol) in tetrachloromethane media have been studied, under the pseudo-first order conditions, in the presence and absence of pyridine as catalyst by variable temperature UV–vis spectrophotometry. Under the kinetic conditions, both the slower uncatalyzed and faster catalyzed (by pyridine) paths give the change of absorbance of the reaction mixture at some wavelength. The obtained values for rate constants have shown that the reactions with phenylselenenyl bromide are slower. Also, the reactions of both phenylselenenyl halides with hex-5-en-1-ol are faster than those with pent-4-en-1-ol. The negative values for entropy of activation for all studied reactions confirm the S_N2 mechanism of substitution.