Pt dispersion control in Pt/SiO₂ by calcination temperature using chloroplatinic acid as catalyst precursor

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• 作者：Shinji Kaneko¹ ; Miyuki Izuka ; Asako Takahashi ; Masaaki Ohshima ; Hideki Kurokawa ; Hiroshi Miura ; ^{hmiura@mail.saitama-u.ac.jp}
• 关键词：Platinum silica catalyst ; Platinum dispersion ; Calcination temperature ; Platinum precursor ; Dispersed PtCl2
• 刊名：Applied Catalysis A ; General
• 出版年：2012
• 期刊代码：4_0926860x
• 类别：ch
• 出版时间：15 June, 2012
• 卷：427-428
• 期：Complete
• 页码：85-91
• 文件大小：907 K

摘要

The effect of pretreatment conditions on the dispersion of Pt/SiO₂ was studied. The catalysts were prepared by impregnation with H₂PtCl₆ as the Pt precursor. Direct reduction of the supported Pt precursor in hydrogen flow was compared to calcinations of the precursor in air flow at various temperatures followed by reduction in hydrogen flow. When the supported precursor was directly reduced in hydrogen flow, Pt dispersion was independent of the reduction temperature. In contrast, when the supported precursor was calcined and then reduced, Pt dispersion was not affected by the reduction temperature but depended heavily on the calcination temperature, ranging widely from 7 to 70%. A good correlation was seen between the particle size calculated from CO adsorption and that observed with transmission electron microscope. Furthermore, it was found that calcination at the temperature at which PtCl₂ is stable gives the highest Pt dispersion. X-ray fluorescence analysis of the calcined samples confirmed the formation of PtCl₂. High Pt dispersion after calcination at optimum temperature was also corroborated with X-ray diffraction analysis from the absence of sharp diffraction peaks. The results suggest that prompt formation and redispersion of PtCl₂ caused high Pt dispersion.