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Anaerobic digestion of glycerol and co-digestion of glycerol and pig manure
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摘要
The potential of glycerol obtained from transesterification of waste cooking oil as a main carbon source for biogas production was investigated. The glycerol was highly contaminated with oils and fats and was pretreated with sulfuric acid. Using a carbon source of glucose as a control, we compared biogas production from the acid-treated glycerol in a synthetic medium and the acid-treated glycerol mixed with pig manure. The anaerobic digestion of acid-treated glycerol with supplement in a synthetic medium was found to be satisfactory at organic loading rates (OLR) between 1.3, 1.6 and 2.6聽g chemical oxygen demand (COD) L鈭? d鈭?. The maximum methane yield of 0.32聽L at Standard temperature and pressure (STP) g鈭? COD removal was achieved at an OLR of 1.6聽g COD聽L鈭? d鈭? and the methane content was 54%on an average. At a higher organic loading rate of 5.4聽g COD聽L鈭? d鈭?, the propionic acid to acetic acid ratio was higher than the critical threshold limit for metabolic imbalance. Anaerobic digestion of acid-treated glycerol with pig manure was also investigated at the COD ratio of 80:20 (glycerol:pig manure). The anaerobic digestion of acid-treated glycerol with pig manure was found to be satisfactory at organic loading rates between 1.3, 1.7, 2.9 and 5.0聽g COD聽L鈭? d鈭? in terms of COD reduction (>80%) and methane content of (62%on an average). However, the biogas production rate was found to significantly decrease at the highest load. The maximum methane yield of 0.24聽L STP聽g鈭? COD removal was achieved at an OLR of 1.3聽g COD聽L鈭? d鈭?.

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