Chemisorption of hydrogen sulphide on zinc oxide modified aluminum-substituted SBA-15

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• 作者：Xiaohui Wang ; Jinping Jia ; Ling Zhao ; Tonghua Sun
• 关键词：Adsorption ; Hydrogen sulphide ; Mesostructure ; Desulphurization ; Zinc oxide nanostructure
• 刊名：Applied Surface Science
• 出版年：2008
• 期刊代码：6_01694332
• 类别：ms
• 出版时间：30 June 2008
• 卷：254
• 期：17
• 页码：5445-5451
• 文件大小：1278 K

摘要

Aluminum silicate mesoporous material, ZnO/Al–SBA-15, was synthesized by post-synthesis and immobilization method via microwave-assisted route. Desulphurization tests from a gas mixture with low content H₂S were carried out as the probing reaction on these materials. Chemical effects and the nature of the ZnO additive and textural properties on desulphurization capacity were studied over this material. Material was characterized using N₂ adsorption, XRD, TEM, FTIR, XPS, ICP and other techniques. The analysis suggests that the as-synthesized material had well-ordered hexagonal mesopores and was abundant in micropores. ZnO nanoparticles dispersed well and anchored both in the channel and the wall of mesoporous silica. The material with 2.1 wt.%zinc loading presented the highest H₂S uptake capacity. Both micropores and mesopores are active sites for H₂S capture, especially micropores. The enhancement of H₂S removal capacity was attributed to the integration of the pore structure of mesoporous material and the promising desulphurization properties of ZnO nanoparticles. ZnO/Al–SBA-15 could be an effective alternative to remove H₂S from gaseous streams and it also extends the research of mesoporous material.