摘要
We have studied the microstructure and critical current density (Jc) of Gd–Ba–Cu–O and Y–Ba–Cu–O bulk superconductors. The size of RE2BaCuO5 (RE211) particles trapped in REBa2Cu3Oy (RE123) matrix could be refined by employing ultra-fine RE211 powder as a precursor, which led to high Jc values exceeding 1×105 A/cm2 at 77 K in self-field for Gd–Ba–Cu–O. In the case of Y–Ba–Cu–O, however, the size reduction of Y211 led to inhomogeneous distribution of Y211 particles, in that the volume fraction of Y211 phase largely decreased near a seed crystal. We also studied superconducting properties of (Gd,Y)–Ba–Cu–O bulk material fabricated from precursor of Gd123-Y211. The employment of finely-milled Y211 powders resulted in a dramatic enhancement of Jc values in this system. The maximum Jc value for (Gd,Y)–Ba–Cu–O reached 2.5×105 A/cm2 at 77 K.