Structural study of anodic films formed on aluminum in nitric acid electrolyte
- 作者：Yakovleva ; N.M. ; Anicai ; L. ; Yakovlev ; A.N. ; Dima ; L. ; Khanina ; E.Ya. ; Buda ; M. ; Chupakhina ; E.A.
- 关键词：Anodic oxidation ; Aluminum oxide ; X-ray diffraction ; Scanning electron microscopy
- 刊名：Thin Solid Films
- 出版年：2002
- 期刊代码：78_00406090
- 类别：ph
- 出版时间：September 2, 2002
- 卷：416
- 期：1-2
- 页码：16-23
- 文件大小：710 K
摘要
The paper presents the results of investigations of porous Al anodic films formed in HNO<sub>3sub> electrolytes carried out by means of electrochemical techniques and X-ray diffraction as well as scanning electron microscopy (SEM). It was assumed that both electrochemical formation of a porous oxide and anodic dissolution of metal take place at Al/oxide interface at the same time. The analysis of short-range order (SRO) parameters for relatively high current density, 1×10<sup>3sup> A/m<sup>2sup>, and anodizing time, 10 min, leads to the conclusion that films mainly consist of amorphous alumina with γ′-Al<sub>2sub>O<sub>3sub>-like SRO and a small amount (
s/glyphs/BQ1.GIF>10%) of amorphous aluminum oxyhydroxide. SEM investigation of the films revealed strong dependence of the surface relief on different applied forming conditions. This marked change in the surface relief is discussed taking into account the relatively complex behavior of Al during anodization in HNO<sub>3sub> electrolytes, that involves both electrochemical growth and dissolution processes of anodic film associated with an electrochemical dissolution of aluminum substrate.