类质同象置换对磁铁矿表面反应性的制约机制
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摘要
铁(氢)氧化物矿物对环境物质的地球化学行为有着重要的制约作用。相比于其他铁氧化物,磁铁矿具有一些独特的结构特征与表面性质,而赋予其良好的氧化还原活性。天然磁铁矿结构中广泛存在类质同象置换,探讨类质同象置换对磁铁矿表面反应的制约机制,有助于深刻理解磁铁矿族矿物在环境自净化过程中的作用机制。本文介绍了典型置换离子在磁铁矿结构中的赋存状态,及其对磁铁矿物化性质影响,重点阐述类质同象置换对磁铁矿表面反应性(如吸附、氧化、还原等性能)的制约机制,最后针对已有的相关研究现状以及面临的挑战,为未来的研究方向提出了一些设想和建议。
Iron oxide and/or hydroxide minerals have played important constraints on the geochemical behaviors of environmental substances. Compared to other iron oxides,magnetite has some unique structural characteristics and surface properties,endowing magnetite with good oxidation and reduction activity. The isomorphous substitution occurred widely in the structure of natural magnetite. To discuss the constraint mechanism of isomorphous substitution on the surface reactivity of magnetite will be helpful to deeply understand the mechanism of magnetite-group minerals in the environmental selfpurification process. This paper has firstly introduced the coordinated state of typical substituting cations and their influences on the physicochemical properties of magnetite,then especially elucidated the constraint mechanism of the isomorphous substitution on the surface reactivity of magnetite(e. g.,adsorption,oxidation,and reduction),and finally proposed some tentative plans and suggestions for future research directions in view of the current research status and facing challenges in this field.
Iron oxide and/or hydroxide minerals have played important constraints on the geochemical behaviors of environmental substances. Compared to other iron oxides,magnetite has some unique structural characteristics and surface properties,endowing magnetite with good oxidation and reduction activity. The isomorphous substitution occurred widely in the structure of natural magnetite. To discuss the constraint mechanism of isomorphous substitution on the surface reactivity of magnetite will be helpful to deeply understand the mechanism of magnetite-group minerals in the environmental selfpurification process. This paper has firstly introduced the coordinated state of typical substituting cations and their influences on the physicochemical properties of magnetite,then especially elucidated the constraint mechanism of the isomorphous substitution on the surface reactivity of magnetite(e. g.,adsorption,oxidation,and reduction),and finally proposed some tentative plans and suggestions for future research directions in view of the current research status and facing challenges in this field.
引文
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Flynn E D,Catalano J G.2018.Influence of oxalate on Ni fate during Fe(II)-catalyzed recrystallization of hematite and goethite.Environmental Science&Technology,52(12):6920-6927
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Gorski C A,Scherer M M.2009.Influence of magnetite stoichiometry on FeIIuptake and nitrobenzene reduction.Environmental Science&Technology,43(10):3675-3680
Hamdeh H H,Barghout K,Ho J C,Shand P M,Miller L L.1999.AMossbauer evaluation of cation distribution in titanomagnetites.Journal of Magnetism and Magnetic Materials,191(1-2):72-78
He H P,Zhong Y H,Liang X L,Tan W,Zhu J X,Wang C Y.2015.Natural Magnetite:an efficient catalyst for the degradation of organic contaminant.Scientific Reports,5:10139.
He Y T,Traina S J.2005.Cr(VI)reduction and immobilization by magnetite under alkaline pH conditions:The role of passivation.Environmental Science&Technology,39(12):4499-4504
Huang X P,Hou X J,Song F H,Zhao J C,Zhang L Z.2016.Facet-dependent Cr(VI)adsorption of hematite nanocrystals.Environmental Science&Technology,50(4):1964-1972
Jeon B H,Dempsey B A,Burgos W D.2003.Kinetics and mechanisms for reactions of Fe(II)with iron(III)oxides.Environmental Science&Technology,37(15):3309-3315
Kong S H,Watts R J,Choi J H.1998.Treatment of petroleum-contaminated soils using iron mineral catalyzed hydrogen peroxide.Chemosphere,37(8):1473-1482
Kwan W P,Voelker B M.2003.Rates of hydroxyl radical generation and organic compound oxidation in mineral-catalyzed Fenton-like systems.Environmental Science&Technology,37(6):1150-1158
Larese-Casanova P,Kappler A,Haderlein S B.2012.Heterogeneous oxidation of Fe(II)on iron oxides in aqueous systems:Identification and controls of Fe(III)product formation.Geochimica et Cosmochimica Acta,91:171-186
Li W,Liang X L,An P F,Feng X H,Tan W F,Qiu G H,Yin H,Liu F.2016.Mechanisms on the morphology variation of hematite crystals by Al substitution:The modification of Fe and O reticular densities.Scientific Reports,6:35960
Li Y,Wei G L,He H P,Liang X L,Chu W,Huang D Y,Zhu J X,Tan W,Huang Q X.2018.Improvement of zinc substitution in the reactivity of magnetite coupled with aqueous Fe(II)towards nitrobenzene reduction.Journal of Colloid and Interface Science,517:104-112
Liang X L,He Z S,Tan W,Liu P,Zhu J X,Zhang J,He H P.2015.The oxidation state and microstructural environment of transition metals(V,Co,and Ni)in magnetite:an XAFS study.Physics and Chemistry of Minerals,42(5):373-383
Liang X L,Liu P,He H P,Wei G L,Chen T H,Tan W,Tan F D,Zhu J X,Zhu R L.2016.The variation of cationic microstructure in Mn-doped spinel ferrite during calcination and its effect on formaldehyde catalytic oxidation.Journal of Hazardous Materials,306:305-312
Liang X L,Wei G L,Xiong J,Tan F D,He H P,Qu C C,Yin H,Zhu J X,Zhu R L,Qin Z H,Zhang J.2017.Adsorption isotherm,mechanism,and geometry of Pb(II)on magnetites substituted with transition metals.Chemical Geology,470:132-140
Liang X L,Zhong Y H,He H P,Yuan P,Zhu J X,Zhu S Y,Jiang Z.2012.The application of chromium substituted magnetite as heterogeneous Fenton catalyst for the degradation of aqueous cationic and anionic dyes.Chemical Engineering Journal,191:177-184
Liang X L,Zhong Y H,Tan W,Zhu J X,Yuan P,He H P,Jiang Z.2013.The influence of substituting metals(Ti,V,Cr,Mn,Co and Ni)on the thermal stability of magnetite.Journal of Thermal Analysis and Calorimetry,111(2):1317-1324
Liang X L,Zhong Y H,Zhu S Y,Zhu J X,Yuan P,He H P,Zhang J.2010a.The decolorization of Acid Orange II in non-homogeneous Fenton reaction catalyzed by natural vanadium-titanium magnetite.Journal of Hazardous Materials,181(1-3):112-120
Liang X L,Zhu S Y,Zhong Y H,Zhu J X,Yuan P,He H P,Zhang J.2010b.The remarkable effect of vanadium doping on the adsorption and catalytic activity of magnetite in the decolorization of methylene blue.Applied Catalysis B:Environmental,97(1-2):151-159
Liu H,Lu X C,Li M,Zhang L J,Pan C,Zhang R,Li J,Xiang W L.2018.Structural incorporation of manganese into goethite and its enhancement of Pb(II)adsorption.Environmental Science&Technology,52(8):4719-4727
Liu P,He H P,Wei G L,Liang X L,Qi F H,Tan F D,Tan W,Zhu JX,Zhu R L.2016.Effect of Mn substitution on the promoted formaldehyde oxidation over spinel ferrite:Catalyst characterization,performance and reaction mechanism.Applied Catalysis B:Environmental,182:476-484
Magalh2es F,Pereira M C,Botrel S E C,Fabris J D,Macedo W A,Mendon9a R,Lago R M,Oliveira L C A.2007.Cr-containing magnetites Fe3-xCrxO4:The role of Cr3+and Fe2+on the stability and reactivity towards H2O2reactions.Applied Catalysis A:General,332(1):115-123
Martinez C E,Mc Bride M B.1998.Solubility of Cd2+,Cu2+,Pb2+,and Zn2+in aged coprecipitates with amorphous iron hydroxides.Environmental Science&Technology,32(6):743-748
Minella M,Marchetti G,De Laurentiis E,Malandrino M,Maurino V,Minero C,Vione D,Hanna K.2014.Photo-Fenton oxidation of phenol with magnetite as iron source.Applied Catalysis B:Environmental,154-155:102-109
Mohan D,Pittman C U Jr.2007.Arsenic removal from water/wastewater using adsorbents-A critical review.Journal of Hazardous Materials,142(1-2):1-53
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