Gemini表面活性剂在不同状态下的自组装行为研究进展
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摘要
自Gemini表面活性剂报道以来,受到了研究者和工业界的广泛关注。对于其结构设计、性能研究、工业应用的报道层出不穷。本文综述了Gemini表面活性剂在不同状态下的自组装行为,主要包括水溶液中的自组装、气液界面上的Langmuir单分子膜、离子液晶及气液界面上的晶体生长。分析和展望了今后Gemini表面活性剂自组装体系的研究方向。
Gemini surfactants attracted wide attention from researchers and industry since they were successfully synthesized. There are numerous reports on the structural design,property research and industrial application of Gemini surfactants. The self-assembly behavior of Gemini surfactants at different conditions were depicted,including self-assembly in aqueous solution,Langmuir monolayer at air/water interface,ionic liquid crystal,and crystal growth at air/water interface. The research direction of Gemini surfactants self-assembly system in the future is analyzed and forecasted.
Gemini surfactants attracted wide attention from researchers and industry since they were successfully synthesized. There are numerous reports on the structural design,property research and industrial application of Gemini surfactants. The self-assembly behavior of Gemini surfactants at different conditions were depicted,including self-assembly in aqueous solution,Langmuir monolayer at air/water interface,ionic liquid crystal,and crystal growth at air/water interface. The research direction of Gemini surfactants self-assembly system in the future is analyzed and forecasted.
引文
[1]Sambasivam A,Sangwai V A,Sureshkumar R.Self-assembly of nanoparticle?surfactant complexes with rodlike micelles: A molecular dynamics study[J].Langmuir,2016,32:1214-1219.
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[3]Li Y,Li H G,Chai J L,et al.Self-assembly and rheological properties of a pseudogemini surfactant formed in a salt-free catanionic surfactant mixture in water[J].Langmuir,2015,31:11209-11219.
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[5]Mondal J,Mahanthappa M,Yethiraj A.Self-assembly of Gemini surfactants: A computer simulation study[J].J Phys Chem B,2013,117:4254-4262.
[6]Zana R.Dimeric (Gemini) surfactants:effect of the spacer group on the association behavior in aqueous solution[J].J Colloid Interface Sci,2002,248:203-220.
[7]Zhang Z G,Zheng P Z,Guo Y M,et al The effect of the spacer rigidity on the aggregation behavior of two ester-containing Gemini surfactants[J].Journal of Colloid and Interface Science,2012,379(1):64-71.
[8]Pei X M,Zhao J X,Ye Y Z,et al.Wormlike micelles and gels reinforced by hydrogen bonding in aqueous cationic gemini surfactant systems[J].Soft Matter,2011,7:2953-2960.
[9]Pei X M,You Y,Zhao J X,et al.Adsorption and aggregation of 2-hydroxyl-propanediyl-a,x-bis (dimethyldodecyl ammonium bromide) in aqueous solution: Effect of intermolecular hydrogen-bonding[J].J Colloid Interface Sci,2010,351:457-465.
[10]Pei X M,Zhao J X,Wei X L.Wormlike micelles formed by mixed cationic and anionic gemini surfactants in aqueous solution[J].J Colloid Interface Sci,2011,356:176-181.
[11]Pei X M,Zhao J X,You Y,et al.Wormlike micelle formation and rheological behavior in the aqueous solutions of mixed sulfate Gemini surfactant without spacer group and dodecyltrimethylammonium bromide[J].Chin J Chem,2011,29:2003-2006.
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[15]Zhen L L,Liu K H,Huang D,et al.Structure-property relationship of sulfosuccinic acid diester sodium salt micelles:3D-QSAR model and DPD simulation[J].Journal of Dispersion Science and Technology,2016,37(7):941-948.
[16]赵剑曦.Gemini表面活性剂:联接链在自组织中的作用及意义[J].化学进展,2014,26(8):1339-1351.
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[18]Chen Q B,Liang X D,Wang S L,et al.Cationic Gemini surfactant at the air/water interface[J].Journal of Colloid and Interface Science,2007,314:651-658.
[19]Chen Q B,Zhang D Z,Li R,et al.Effect of the spacer group on the behavior of the cationic Gemini surfactant monolayer at the air/water interface[J].Thin Solid Films,2008,516:8782-8787.
[20]Xu S H,Liu A P,Chen Q B,et al.Self-assembly nano-structure of type I collagen adsorbed on Gemini surfactant LB monolayers[J].Colloids and Surfaces B: Biointerfaces,2009,70:124-131.
[21]Chen Q B,Kang X L,Li R,et al.Structure of the complex monolayer of Gemini surfactant and DNA at the air/water interface[J].Langmuir,2012,28:3429-3438.
[22]Arkas M,Tsiourwas D,Paleos C M,et al.Smectic mesophases from dihydroxy derivatives of quaternary alkylammonium salts[J].Chem Eur J,1999:3202-3207.
[23]Song B L,Shang S B,Song Z Q.Solution behavior and solid phase transitions of quaternary ammonium surfactants with head groups decorated by hydroxyl groups[J].J Colloid Interface Sci,2012,382:53-60.
[24]Wei Z B,Wei X L,Wang X H,et al.Ionic liquid crystals of quaternary ammonium salts with a 2-hydroxypropoxy insertion group[J].J Mater Chem,2011,21:6875-6882.
[25]魏西莲,魏增斌,傅式洲,等.1-烷基-3-甲基咪唑溴化盐离子液体的晶体结构及性能[J].中国科学:化学,2010,40(8):1072-1079.
[26]Jura?in D,Pustak A,Habu? I,et al.Polymorphism and mesomorphism of oligomeric surfactants: effect of the degree of oligomerization[J].Langmuir,2011,27:14118-14130.
[27]Zhou T H,Zhao J X.Synthesis and thermotropic liquid crystalline properties of heterogemini surfactants containing a quaternary ammonium and a hydroxyl group[J].J Colloid Interface Sci,2009,331:476-483.
[28]Wei Z B,Wei X L,Sun D Z,et al.Crystalline structures and mesomorphic properties of gemini diammonium surfactants with a pendant hydroxyl group[J].J Colloid Interface Sci,2011,354:677-685.
[29]Wang X D,Chen X,Zhao Y R,et al.Nonaqueous lyotropic liquid-crystalline phases formed by Gemini surfactants in a protic ionic liquid[J].Langmuir,2012,28:2476-2484.
[30]宋冰蕾,陈涛,田金年,等.Gemini 型表面活性剂在离子液体中构筑的溶致液晶[J].化工进展,2015,34(12):4348-4355.
[31]Zhou M,Liu H L,Yang H F,et al.Spontaneous crystallization at the air-water interface: An unusual feature of Gemini surfactant with a rigid spacer[J].Langmuir,2006,22:10877-10879.
[32]Chen Q B,Yao J Y,Hu X,et al.Monolayer effect of a gemini surfactant with a rigid biphenyl spacer on its self-crystallization at the air/liquid interface[J].J Appl Cryst,2015,48:728-735.
[33]Yao J Y,Chen Q B,Sheng Y J,et al.pH-controlled crystal growth of copper/gemini surfactant complexes with bipyridine groups[J].Cryst Eng Comm,2017,19:5835-5843.
[2]Zhao J X,Xu X Z,Dong W J,et al. Self-assembly of some long-tail surfactants driven by water addition in ethanol[J].Colloid Surface A,2015,484:253-261.
[3]Li Y,Li H G,Chai J L,et al.Self-assembly and rheological properties of a pseudogemini surfactant formed in a salt-free catanionic surfactant mixture in water[J].Langmuir,2015,31:11209-11219.
[4]Zana R.Dimeric and oligomeric surfactants. Behavior at interfaces and in aqueous solution: a review[J].Adv Colloid Interface Sci,2002,97:205-253.
[5]Mondal J,Mahanthappa M,Yethiraj A.Self-assembly of Gemini surfactants: A computer simulation study[J].J Phys Chem B,2013,117:4254-4262.
[6]Zana R.Dimeric (Gemini) surfactants:effect of the spacer group on the association behavior in aqueous solution[J].J Colloid Interface Sci,2002,248:203-220.
[7]Zhang Z G,Zheng P Z,Guo Y M,et al The effect of the spacer rigidity on the aggregation behavior of two ester-containing Gemini surfactants[J].Journal of Colloid and Interface Science,2012,379(1):64-71.
[8]Pei X M,Zhao J X,Ye Y Z,et al.Wormlike micelles and gels reinforced by hydrogen bonding in aqueous cationic gemini surfactant systems[J].Soft Matter,2011,7:2953-2960.
[9]Pei X M,You Y,Zhao J X,et al.Adsorption and aggregation of 2-hydroxyl-propanediyl-a,x-bis (dimethyldodecyl ammonium bromide) in aqueous solution: Effect of intermolecular hydrogen-bonding[J].J Colloid Interface Sci,2010,351:457-465.
[10]Pei X M,Zhao J X,Wei X L.Wormlike micelles formed by mixed cationic and anionic gemini surfactants in aqueous solution[J].J Colloid Interface Sci,2011,356:176-181.
[11]Pei X M,Zhao J X,You Y,et al.Wormlike micelle formation and rheological behavior in the aqueous solutions of mixed sulfate Gemini surfactant without spacer group and dodecyltrimethylammonium bromide[J].Chin J Chem,2011,29:2003-2006.
[12]裴晓梅,赵剑曦,魏西莲.水杨酸钠对阳离子Gemini表面活性剂水溶液中蠕虫状胶束形成和性质的影响[J].物理化学学报,2011,27(4):913-917.
[13]Bao Y,Guo J J,Ma J Z,et al.Cationic silicon-based gemini surfactants: Effect of hydrophobic chains on surface activity,physic-chemical properties and aggregation behaviors[J].Journal of Industrial and Engineering Chemistry,2017,53:51-61.
[14]Xu Y,Guo S Y,Mao X J,et al.Molecular simulation study on the self-assembly behaviors of zwitterionic heterogemini surfactant in aqueous solution[J].Journal of Dispersion Science and Technology,2018,39(3):443-451.
[15]Zhen L L,Liu K H,Huang D,et al.Structure-property relationship of sulfosuccinic acid diester sodium salt micelles:3D-QSAR model and DPD simulation[J].Journal of Dispersion Science and Technology,2016,37(7):941-948.
[16]赵剑曦.Gemini表面活性剂:联接链在自组织中的作用及意义[J].化学进展,2014,26(8):1339-1351.
[17]范雅珣,韩玉淳,王毅琳.Gemini表面活性剂分子结构对其水溶液中聚集行为的影响[J].物理化学学报,2016,32(1):214-226.
[18]Chen Q B,Liang X D,Wang S L,et al.Cationic Gemini surfactant at the air/water interface[J].Journal of Colloid and Interface Science,2007,314:651-658.
[19]Chen Q B,Zhang D Z,Li R,et al.Effect of the spacer group on the behavior of the cationic Gemini surfactant monolayer at the air/water interface[J].Thin Solid Films,2008,516:8782-8787.
[20]Xu S H,Liu A P,Chen Q B,et al.Self-assembly nano-structure of type I collagen adsorbed on Gemini surfactant LB monolayers[J].Colloids and Surfaces B: Biointerfaces,2009,70:124-131.
[21]Chen Q B,Kang X L,Li R,et al.Structure of the complex monolayer of Gemini surfactant and DNA at the air/water interface[J].Langmuir,2012,28:3429-3438.
[22]Arkas M,Tsiourwas D,Paleos C M,et al.Smectic mesophases from dihydroxy derivatives of quaternary alkylammonium salts[J].Chem Eur J,1999:3202-3207.
[23]Song B L,Shang S B,Song Z Q.Solution behavior and solid phase transitions of quaternary ammonium surfactants with head groups decorated by hydroxyl groups[J].J Colloid Interface Sci,2012,382:53-60.
[24]Wei Z B,Wei X L,Wang X H,et al.Ionic liquid crystals of quaternary ammonium salts with a 2-hydroxypropoxy insertion group[J].J Mater Chem,2011,21:6875-6882.
[25]魏西莲,魏增斌,傅式洲,等.1-烷基-3-甲基咪唑溴化盐离子液体的晶体结构及性能[J].中国科学:化学,2010,40(8):1072-1079.
[26]Jura?in D,Pustak A,Habu? I,et al.Polymorphism and mesomorphism of oligomeric surfactants: effect of the degree of oligomerization[J].Langmuir,2011,27:14118-14130.
[27]Zhou T H,Zhao J X.Synthesis and thermotropic liquid crystalline properties of heterogemini surfactants containing a quaternary ammonium and a hydroxyl group[J].J Colloid Interface Sci,2009,331:476-483.
[28]Wei Z B,Wei X L,Sun D Z,et al.Crystalline structures and mesomorphic properties of gemini diammonium surfactants with a pendant hydroxyl group[J].J Colloid Interface Sci,2011,354:677-685.
[29]Wang X D,Chen X,Zhao Y R,et al.Nonaqueous lyotropic liquid-crystalline phases formed by Gemini surfactants in a protic ionic liquid[J].Langmuir,2012,28:2476-2484.
[30]宋冰蕾,陈涛,田金年,等.Gemini 型表面活性剂在离子液体中构筑的溶致液晶[J].化工进展,2015,34(12):4348-4355.
[31]Zhou M,Liu H L,Yang H F,et al.Spontaneous crystallization at the air-water interface: An unusual feature of Gemini surfactant with a rigid spacer[J].Langmuir,2006,22:10877-10879.
[32]Chen Q B,Yao J Y,Hu X,et al.Monolayer effect of a gemini surfactant with a rigid biphenyl spacer on its self-crystallization at the air/liquid interface[J].J Appl Cryst,2015,48:728-735.
[33]Yao J Y,Chen Q B,Sheng Y J,et al.pH-controlled crystal growth of copper/gemini surfactant complexes with bipyridine groups[J].Cryst Eng Comm,2017,19:5835-5843.