分子筛催化剂在染料降解中的应用研究进展
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摘要
综述了分子筛负载的钛化合物、铁化合物以及杂多酸在催化有机染料降解中的应用。常见的分子筛载体主要有二氧化硅分子筛、SBA-15、MCM-41和ZSM-5等。光催化剂负载于分子筛后,在催化不同染料降解时通常表现出十分优异的性能,一般均要高于同等条件下均相光催化剂的催化效率。另外,与均相催化剂相比,分子筛负载型光催化剂的回收再生性能更加优异。
The application of molecular sieve loaded titanium compounds, iron compounds and hetero-polyacids in the degradation of organic dyes was reviewed. The typical molecular sieve carriers were silica sieves, SBA-15, MCM-41 and ZSM-5. When the photo-catalysts were loaded on molecular sieves, excellent performance in the degradation of dyes could be observed. The supported catalysts showed higher catalytic activities than that of homogeneous photo-catalysts under the same conditions. In addition, compared with the homogeneous catalysts, the recovery and regeneration performance of the zeolite supported photo-catalysts were more excellent.
The application of molecular sieve loaded titanium compounds, iron compounds and hetero-polyacids in the degradation of organic dyes was reviewed. The typical molecular sieve carriers were silica sieves, SBA-15, MCM-41 and ZSM-5. When the photo-catalysts were loaded on molecular sieves, excellent performance in the degradation of dyes could be observed. The supported catalysts showed higher catalytic activities than that of homogeneous photo-catalysts under the same conditions. In addition, compared with the homogeneous catalysts, the recovery and regeneration performance of the zeolite supported photo-catalysts were more excellent.
引文
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[2]李凤霄,王彦博,杜夕铭,等.絮凝法处理印染废水的研究进展[J].中国科技纵横,2015(20):2.
[3]刘路.纺织印染废水处理技术研究现状及进展[J].上海工程技术大学学报,2017,31(2):174-177.
[4]MARTíNEZ-HUITLE C A,BRILLAS E.Decontamination of wastewa-ters containing synthetic organic dyes by electrochemical methods:Ageneral review[J].Applied Catalysis B Environmental,2009,87(3-4):105-145.
[5]VERMA A K,DASH R R,BHUNIA P.A review on chemical coagula-tion/flocculation technologies for removal of colour from textile waste-waters[J].Journal of Environmental Management,2012,93(1):154-168.
[6]SAKKAYAWONG N,THIRAVETYAN P,NAKBANPOTE W.Adsorp-tion mechanism of synthetic reactive dye wastewater by chitosan[J].Journal of Colloid&Interface Science,2005,286(1):36-42.
[7]张鹏会,李艳春,胡浩斌,等.B、N和Ce共掺杂TiO2光催化降解染料废水研究[J].化工新型材料,2016(3):229-231.
[8]唐长存,李永刚,黄应平,等.Na F浸泡处理对BiOBr光催化降解有机染料罗丹明B的影响[J].分子催化,2017,31(2):169-180.
[9]郭靖茹,韩枫,李春荣,等.Cu掺杂TiO2光催化剂降解有机染料的研究[J].应用化工,2016,45(4):653-656.
[10]石淑云,任百祥.新型杂多酸盐光催化降解亚甲基蓝染料废水[J].应用化学,2016,33(5):577-582.
[11]王宽岭,张文杰,段卫宇.HZSM-5分子筛负载Fe掺杂Ti 2的制备及光催化性能研究[J].电镀与精饰,2016,38(5):11-15.
[12]杨丽丽,李传国,王宏,等.HZSM-5分子筛负载Sr TiO3光催化降解活性艳红X-3B[J].复合材料学报,2016,33(11):2 682-2 687.
[13]吴强顺,王慧娟,周广顺,等.TS-1分子筛的制备及光催化降解偶氮染料AO7[J].印染,2016(20):1-5.
[14]刘群,丁斌,郝凤岭,等.TS-1分子筛光催化氧化降解偶氮染料直接湖蓝5B[J].印染,2015(23):11-14.
[15]陶红,张宇然,王璐,等.13X分子筛负载TiO2对偶氮染料活性艳红的光催化降解[J].水资源与水工程学报,2010,21(2):79-82.
[16]关卫省,赵欢,霍鹏伟,等.表面包覆TiO2材料的制备及光催化降解染料废水[J].环境科学与技术,2013(4):132-136.
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[18]王侃.负载型TiO2催化剂可见光降解染料污染物的研究[D].杭州:浙江大学,2004.
[19]靳琳,李增和,李歌,等.由粉煤灰制备MCM-41及其负载纳米TiO2的光催化性能研究[J].化工科技,2016,24(3):39-45.
[20]陈娴,高永,徐旭,等.Fe Y催化剂光助Fenton法降解亚甲基蓝染料废水[J].环境科学与技术,2012,35(2):139-142.
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[25]成岳,潘顺龙,焦创,等.Fe-MEL分子筛催化剂的制备及其催化脱色[J].过程工程学报,2012,12(1):148-153.
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[27]尚筱洁.Fe-Ti-分子筛催化剂的制备及其光催化性能研究[D].兰州:兰州大学,2007.
[28]黄艳芹,周建伟,程玉良,等.PW/MCM-41光催化降解亚甲基蓝溶液研究[J].河南师范大学学报:自然科学版,2010,38(2):120-122.
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[30]黄艳芹,程玉良,周建伟.PW/MCM-41光催化性能研究[J].工业水处理,2011,31(8):52-54.
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