二氧化碳化学转化技术研究进展
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摘要
将二氧化碳(CO_2)转化为高附加值的化学品和燃料被认为是21世纪的巨大挑战,如何高效活化CO_2是将其资源化利用的重要环节。针对常见的CO_2转化策略,如CO_2分解反应、CO_2与氢化合物(氢气、甲烷、水)反应,讨论了催化转化、电化学还原、太阳能热、等离子转化技术以及各新技术协同催化技术在CO_2活化转化领域中最新应用进展。从转化率和能效的角度强调了多学科交叉的重要性,并对未来CO_2转化发展进行了展望。
CO_2 conversion into value-added chemicals and fuels is considered as one of the greatest challenges of the 21 st century. The important part of its resource utilization is to find method and technology to effectively and efficiently activate CO_2 molecule. In general,the common chemical conversion strategies,including pure CO_2 splitting and conversion of CO_2 with hydrogen source compound like hydrogen( H_2),methane( CH_4) and steamed water( H_2O),have been briefly reviewed. In this paper,after exploring traditional thermodynamic limitation,several novel technologies are investigated,such as electrochemical reduction,solar thermochemical,photochemical and plasma technology,either with or without catalysts,as well as their great potentials in recent years applied in the CO_2 conversion fields. Conversion rate and energy efficiency were used to demonstrate the importance of the muti-disciplinary efforts. Finally,the challenge and prospects for the further development of CO_2 conversion has been presented.
CO_2 conversion into value-added chemicals and fuels is considered as one of the greatest challenges of the 21 st century. The important part of its resource utilization is to find method and technology to effectively and efficiently activate CO_2 molecule. In general,the common chemical conversion strategies,including pure CO_2 splitting and conversion of CO_2 with hydrogen source compound like hydrogen( H_2),methane( CH_4) and steamed water( H_2O),have been briefly reviewed. In this paper,after exploring traditional thermodynamic limitation,several novel technologies are investigated,such as electrochemical reduction,solar thermochemical,photochemical and plasma technology,either with or without catalysts,as well as their great potentials in recent years applied in the CO_2 conversion fields. Conversion rate and energy efficiency were used to demonstrate the importance of the muti-disciplinary efforts. Finally,the challenge and prospects for the further development of CO_2 conversion has been presented.
引文
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[19]景维云,毛庆,石越,等.CO2电催化还原制烃类产物的研究进展[J].化工学报,2017,36(6):2150-2157.
[20]蒋青青,童金辉,陈真盘,等.太阳能光热化学分解CO2和H2O的研究进展[J].中国科学:化学,2014,44(12):1834-1848.
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[24]张渊.光催化剂微纳结构调控及应用于二氧化碳光还原[D].南京:南京大学,2017.
[25]王尔超,王加跑,曹先婷,等.二氧化碳的化学转化方法研究进展[J].杭州师范大学学报(自然科学版),2016,15(5):509-513.
[26]朱凯建,罗文俊,关中杰,等.光电化学分解水电池的电极性能提高方法及光阴极研究进展[J].电化学,2016,22(4):368-381.
[27]Jackson P,Hariskos D,Lotter E,et al.New world record efficiency for Cu(In,Ga)Se2thin-film solar cells beyond20%[J].Progress in Photovoltaics,2011,19(7):894-897.
[28]Chen G,Britun N,Godfroid T,et al.An overview of CO2conversion in a microwave discharge:the role of plasmacatalysis[J].J Phys D:Appl Phys,2017,50:84001.
[29]朱斌.火花放电等离子体中甲烷的CO2重整与复合复整[D].大连:大连理工大学,2013.
[30]Li D,Li X,Bai M,et al.CO2reforming of CH4by atmospheric pressure glow discharge plasma:A high conversion ability[J].Int J Hydrogen Energy,2009,34:308-313.
[31]黄秋实,兰俐颖,王安杰,等.二氧化碳甲烷化反应中等离子体与Ni/ZSM-5催化剂的协同作用[J].石油化工,2017,46(11):1355-1360.
[32]吴帆.等离子体法分解CO2的反应动力学研究[D].大连:大连理工大学,2017.
[33]Kumar B,Llorente M,Froehlich J,et al.Photochemical and photoelectrochemical reduction of CO2[J].Annu Rev Phys Chem,2012,63:541-569.
[34]Wei J,Ge Q J,Yao R W,et al.Directly converting CO2into a gasoline fuel[J].Nat Commun,2017:15174.
[35]Gao P,Li S G,Bu X N,et al.Direct conversion of CO2into liquid fuels with high selectivity over a bifunctional catalyst[J].Nature Chem,2017:2794.
[36]黄冲.Cu O-Zn O-Zr O2的微波辅助法制备及其催化CO2加氢制甲醇反应性能[D].上海:上海应用技术大学,2017.
[37]张梦.载铂石墨烯协同Ti O2纳米管光电催化还原CO2的机理研究[D].杭州:浙江大学,2016.
[38]周天辰,何川,张亚男,等.CO2的光电催化还原[J].化学进展,2012,24(10):1897-1905.
[39]朱俊志.铁基泡沫陶瓷催化剂CO2微波重整CH4试验研究[D].济南:山东大学,2017.
[40]于伟超.微波诱导碳基催化剂催化甲烷裂解及重整制氢的实验研究[D].上海:东华大学,2014.
[41]Navarrete A,Centi G,Bogaerts A,et al.Harvesting renewable energy for carbon dioxide catalysis[J].Energy Technol,2017,5:796-811.
[2]Goeppert A,Czaun M,Jones J P,et al.Recycling of carbon dioxide to methanol and derived products-closing the loop[J].Chem Soc Rev,2014,46(6):7995-8048.
[3]Ramses S,Annemie B.Plasma technology-a novel solution for CO2conversation?[J].Chem Soc Rev,2017,46(19):5805-5863.
[4]李凤姣.二氧化碳间接合成有机醇酯多相催化体系研究[D].北京:中国科学院大学,2016.
[5]兰东辉.二氧化碳资源化为环状碳酸酯的新型碳基催化剂研究[D].长沙:湖南大学,2016.
[6]Nigara Y,Cales B.Production of CO by direct thermal splitting of CO2at high temperature[J].Bull Chem Soe JPn,1986,59:1997-2002.
[7]张鹏,金万勤,范益群,等.钙钛矿型混合导体透氧膜用于CO2高温分解反应的研究[C]//第一届全国化学工程与生物化工年会论文摘要集(上).北京:中国化工学会,2004:405.
[8]刘树森,朱继宇,张志磊,等.CO2甲烷化研究进展[J].工业催化,2018,26(1):1-12.
[9]Aziz M A A,Jalil A A,Triwahyono S,et al.CO2methanation over heterogeneous catalysts:recent progress and future prospects.[J].Green Chem,2015,17:2647-2663.
[10]Younas M,Loong K L,Bashir M J K,et al.Recent advancements,fundamental challenges,and opportunities in catalytic methanation of CO2[J].Energy&Fuels,2016,30(11):8815-8831.
[11]Gotz M,Lefebvre J,Mors F,et al.Renewable power-togas:A technological and economic review[J].Renewable Energy,2016,85:1371-1390.
[12]刘昌俊,郭秋婷,叶静云,等.二氧化碳转化催化剂研究进展及相关问题思考[J].化学学报,2016,67(1):6-13.
[13]Kortlever R,Peters I,Koper S,et al.Electrochemical CO2reduction to formic acid at low over-potential and with high faradaic efficiency on carbon supported bimetallic Pd-Pt nanoparticles[J].ACS Catal,2015,5:3916-3923.
[14]白晓芳,陈为,王白银,等.二氧化碳电化学还原的研究进展[J].物理化学学报,2017,33(12):2388-2403.
[15]Qiao J,Liu Y,Hong F,et al.A review of catalysts for the electro-reduction of carbon dioxide to produce low-carbon fuels[J].Chem Soc Rev,2013,43(2):631-675.
[16]李亚楠.纳米氧化锡催化剂及其膜电极的制备及CO2电催化还原性能研究[D].上海:东华大学,2017.
[17]Hollingsworth N,Taylor S F R,Galante M T,et al.Reduction of carbon dioxide to formate at low over-potential using a super base ionic liquid[J].Angew Chem Int Ed,2015,54(47):14164-14168.
[18]冯建鹏,张香平,尚大伟,等.离子液体中电化学还原CO2研究评述与展望[J].化工学报,2018,69(1):69-75.
[19]景维云,毛庆,石越,等.CO2电催化还原制烃类产物的研究进展[J].化工学报,2017,36(6):2150-2157.
[20]蒋青青,童金辉,陈真盘,等.太阳能光热化学分解CO2和H2O的研究进展[J].中国科学:化学,2014,44(12):1834-1848.
[21]Greg P S,Aldo S.Photochemical and thermochemical[J].Ind Eng Chem Res,2012,51(37):11828-11840.
[22]Romero M,Steinfeld A.Concentrating solar thermal power and thermochemical fuels[J].Energy Environ Sci,2012(5):9234-9245.
[23]Li K,An X,Park K,et al.A critical review of CO2photo conversion:Catalysts and reactors[J].Catalysis Today,2014,224:3-12.
[24]张渊.光催化剂微纳结构调控及应用于二氧化碳光还原[D].南京:南京大学,2017.
[25]王尔超,王加跑,曹先婷,等.二氧化碳的化学转化方法研究进展[J].杭州师范大学学报(自然科学版),2016,15(5):509-513.
[26]朱凯建,罗文俊,关中杰,等.光电化学分解水电池的电极性能提高方法及光阴极研究进展[J].电化学,2016,22(4):368-381.
[27]Jackson P,Hariskos D,Lotter E,et al.New world record efficiency for Cu(In,Ga)Se2thin-film solar cells beyond20%[J].Progress in Photovoltaics,2011,19(7):894-897.
[28]Chen G,Britun N,Godfroid T,et al.An overview of CO2conversion in a microwave discharge:the role of plasmacatalysis[J].J Phys D:Appl Phys,2017,50:84001.
[29]朱斌.火花放电等离子体中甲烷的CO2重整与复合复整[D].大连:大连理工大学,2013.
[30]Li D,Li X,Bai M,et al.CO2reforming of CH4by atmospheric pressure glow discharge plasma:A high conversion ability[J].Int J Hydrogen Energy,2009,34:308-313.
[31]黄秋实,兰俐颖,王安杰,等.二氧化碳甲烷化反应中等离子体与Ni/ZSM-5催化剂的协同作用[J].石油化工,2017,46(11):1355-1360.
[32]吴帆.等离子体法分解CO2的反应动力学研究[D].大连:大连理工大学,2017.
[33]Kumar B,Llorente M,Froehlich J,et al.Photochemical and photoelectrochemical reduction of CO2[J].Annu Rev Phys Chem,2012,63:541-569.
[34]Wei J,Ge Q J,Yao R W,et al.Directly converting CO2into a gasoline fuel[J].Nat Commun,2017:15174.
[35]Gao P,Li S G,Bu X N,et al.Direct conversion of CO2into liquid fuels with high selectivity over a bifunctional catalyst[J].Nature Chem,2017:2794.
[36]黄冲.Cu O-Zn O-Zr O2的微波辅助法制备及其催化CO2加氢制甲醇反应性能[D].上海:上海应用技术大学,2017.
[37]张梦.载铂石墨烯协同Ti O2纳米管光电催化还原CO2的机理研究[D].杭州:浙江大学,2016.
[38]周天辰,何川,张亚男,等.CO2的光电催化还原[J].化学进展,2012,24(10):1897-1905.
[39]朱俊志.铁基泡沫陶瓷催化剂CO2微波重整CH4试验研究[D].济南:山东大学,2017.
[40]于伟超.微波诱导碳基催化剂催化甲烷裂解及重整制氢的实验研究[D].上海:东华大学,2014.
[41]Navarrete A,Centi G,Bogaerts A,et al.Harvesting renewable energy for carbon dioxide catalysis[J].Energy Technol,2017,5:796-811.
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