八乙基卟啉锌薄膜玻璃光波导传感器的制备及气敏性研究
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摘要
利用旋转-甩涂法(spin-coating)将八乙基卟啉锌薄膜固定在K+交换玻璃光波导表面,制成八乙基卟啉锌膜/K+交换玻璃光波导敏感元件。优化敏感元件的制备条件,检测了16种有机挥发性气体的选择性响应。实验结果表明,该敏感元件对甲苯具有较高的灵敏度,检测限为1×10-9(V/V0; V:被检测气体体积,V0:空气体积)体积比,信噪比S/N=3.88,响应时间和回复时间分别为2.4 s和11 s,平行测定五次试验,其结果具有良好的线性关系(R=0.994 8),相对标准偏差RSD=1.24%,八乙基卟啉锌薄膜厚度为(120±5) nm,折射率为1.753 5。
Octaethylporphyrin Zinc film/K+exchanged glass optical waveguide sensor was fabricated and the octaethylporphyrin Zinc compound was fixed on K+glass optical waveguide surface by the method of spin-coating. The experimental results show that the sensing element has a high sensitivity to toluene. The detection limit was 1×10-9 V/V0( S/N = 3. 88),the response time and recovery time was 2. 4 s and 11 s,respectively. In the parallel experiment,the results also had a good linear relationship( R = 0.9948),the relative standard deviation was 1.24%,Meanwhile.the thickness of octaethylporphyrin Zinc film is( 120±5) nm,The refractive index is 1.753 5.
Octaethylporphyrin Zinc film/K+exchanged glass optical waveguide sensor was fabricated and the octaethylporphyrin Zinc compound was fixed on K+glass optical waveguide surface by the method of spin-coating. The experimental results show that the sensing element has a high sensitivity to toluene. The detection limit was 1×10-9 V/V0( S/N = 3. 88),the response time and recovery time was 2. 4 s and 11 s,respectively. In the parallel experiment,the results also had a good linear relationship( R = 0.9948),the relative standard deviation was 1.24%,Meanwhile.the thickness of octaethylporphyrin Zinc film is( 120±5) nm,The refractive index is 1.753 5.
引文
[1]徐艳平,顾铮先,陈家璧.光化学传感器及其最新进展[J].光学仪器,2004,26(4):57-61.
[2]史婷婷,姬东方,于艳敏.卟啉聚集行为的研究进展[J].材料导报,2017,31(5):46-52.
[3]马红,韩士田.卟啉在催化剂方面的应用研究进展[J].河北工业科技,2009,26(3):205-209.
[4]胡建新,李凤清,周雪琴,等.卟啉-多肽超分子组装体系的研究进展[J].材料导报,2017,31(11):128-137.
[5]徐海云,胡春华,冯翠兰.卟啉类有机化合物在染料敏化太阳能电池的应用研究进展[J].应用化工,2011,40(8):1451-1457.
[6] Bernini R,Tonezzer M,Mottoa F,et al. Volatile Organic Compounds Detection Using Porphyrin-Based Metal-Cladding Leaky Waveguides[J]. Sensors and Actuators B,2007,B(127),231-236.
[7]何育苗.甲苯硝化间位选择性的研究[D].南京:南京理工大学,2008.
[8]吕天峰,袁懋,吕怡兵,等. 2007-2015年北京市室内环境空气污染状况及防治措施[J].环境化学,2016,35(10):2191-2196.
[9] Lee C,Yoon J. UV-A Induced Photochemical Formation of Nnitrosodimethylamine(NDMA)in the Presence of Nitrite and Dimethylamine[J]. Journal of Photochemistry&Photobiology A Chemistry,2007,189(1):128-134.
[10] Xu S X,Zhang L L,Zhang H C,et al. A Salt-Assisted Graphene Oxide Aggregation Method for the Determination of Dimethylamine and Trimethylamine by Ion Chromatography with Conductivity Detection[J]. Analytical Methods,2016,8(8):1828-1835.
[11]王慧文.高效液相色谱技术在药品检验中的应用及进展[J].安徽医药,2008,12(11):1087-1091.
[12] Lander B Z,Alejandro B. A Novel Liquid Chromatography-Mass Spectrometric Method for the Simultaneous Determination of Trimethylamine,Dimethylamine and Methylamine in Fishery Products[J]. Food Chem,2016,196,1207-1214.
[13]朱欣瑶,赛永竹,张晓静,等.实验室中有害气体苯、甲苯、甲醇和丙酮的检测分析[J].中国中医药现代远程教育,2013,11(4):157-160.
[14]李涛,胡青大,唐冬宝.新型C[6]/Si O2/CdTe NPs荧光探针对乙二胺的识别和检测[J].化工管理,2015(16):184-185.
[15]姑力米热·吐尔地,帕提曼·尼扎木丁,燕音,等.四苯基卟啉薄膜/K+交换玻璃光波导传感器的研制及其气敏性研究[J].传感技术学报,2016,29(7):966-970.
[16]王佳明,姑力米热·吐尔地,燕音,等.基于四苯基卟啉铁敏感膜的玻璃光波导传感器对乙二胺的响应特性[J].应用化学,2017,34(7):847-854.
[17] Rakow N A,Suslick K S. A Colorimetric Sensor Array for Odour Visualization[J]. Nature,2000,406(6797):710.
[18] Capan 6)I,Erdoˇgan M,Stanciu G A,et al. The Interaction between the Gas Sensing and Surface Morphology Properties of LB Thin Films of Porphyrins in Terms of the Adsorption Kinetics[J]. Materials Chemistry&Physics,2012,136(2-3):1130-1136.
[19] Nizamidin P,Yimit A,Itoh K. Synthesis and Optical-Electrochemical Gas Sensing Application of Ni-Doped Li Fe PO4Nano-Particle[J]. New Journal of Chemistry,2016,40(1):295-301.
[20] YASIN,Patime,YIMIT,et al. Cyclodextrin Polymer Films Optical Waveguide Sensor for Volatile Organic Gas Detection[J].Chemical Resarch in Chinese University,2012,28(4):682-685.
[21]侯长军,刘琛,霍丹群,等.四苯基卟啉铟纳米材料的制备及其光学传感性能研究[J].功能材料,2011,42(6):1155-1158.
[22] Ghosh A,Selvamani T,Jose D A,et al. Generation of Nanostructures by the Aggregation of Porphyrin Derivatives with Long Alkane Chain in Mix-Solvent[J]. Journal of Nanomaterials,2007(1):1-8.
[23] Nizamidin P,Yimit A,Wang J D,et al. Optical Properties and Sensing Applications of Lithium Iron Phosphate Thin Films[J].Thin Solid Films,2012,520(19):6250-6255.
[24] Janzen M C,Ponder J B,Bailey D P,et al. Colorimetric Sensor Arrays for Volatile Organic Compounds[J]. Analytical Chemistry,2006,78(11):3591-3600.
[25] Askim J R,Mahmoudi M,Suslick K S. Chem Inform Abstract:Optical Sensor Arrays for Chemical Sensing:The Optoelectronic Nose[J].Chemical Society Reviews,2013,42(22):8649-8682.
[26] Abdelhamid R F,Obara Y,Uchida Y,et al. Pi-Pi Interaction between Aromatic Ring and Copper-Coordinated Imidazole Regulates the Blue Copper Active-Site Structure[J]. Journal of Biological Inorganic Chemistry,2007,12(2):165-173.
[27]杨菁菁,刘俊刁. SnO2薄膜的电学气敏特性与光学气敏特性研究[J].化学传感器,1999(2):32-35.
[28] Gouterman M. Spectra of Porphyrins[J]. Journal of Molecular Spectroscpy,1961,6,138-163.
[29] Nú1ez-Nieto X,Solla M,Gómez-Pérez P,et al. Signal-to-Noise Ratio Dependence on Ground Penetrating Radar Antenna Frequency in the Field of Landmine and UXO Detection[J].Measurement,2015,73:24-32.
[2]史婷婷,姬东方,于艳敏.卟啉聚集行为的研究进展[J].材料导报,2017,31(5):46-52.
[3]马红,韩士田.卟啉在催化剂方面的应用研究进展[J].河北工业科技,2009,26(3):205-209.
[4]胡建新,李凤清,周雪琴,等.卟啉-多肽超分子组装体系的研究进展[J].材料导报,2017,31(11):128-137.
[5]徐海云,胡春华,冯翠兰.卟啉类有机化合物在染料敏化太阳能电池的应用研究进展[J].应用化工,2011,40(8):1451-1457.
[6] Bernini R,Tonezzer M,Mottoa F,et al. Volatile Organic Compounds Detection Using Porphyrin-Based Metal-Cladding Leaky Waveguides[J]. Sensors and Actuators B,2007,B(127),231-236.
[7]何育苗.甲苯硝化间位选择性的研究[D].南京:南京理工大学,2008.
[8]吕天峰,袁懋,吕怡兵,等. 2007-2015年北京市室内环境空气污染状况及防治措施[J].环境化学,2016,35(10):2191-2196.
[9] Lee C,Yoon J. UV-A Induced Photochemical Formation of Nnitrosodimethylamine(NDMA)in the Presence of Nitrite and Dimethylamine[J]. Journal of Photochemistry&Photobiology A Chemistry,2007,189(1):128-134.
[10] Xu S X,Zhang L L,Zhang H C,et al. A Salt-Assisted Graphene Oxide Aggregation Method for the Determination of Dimethylamine and Trimethylamine by Ion Chromatography with Conductivity Detection[J]. Analytical Methods,2016,8(8):1828-1835.
[11]王慧文.高效液相色谱技术在药品检验中的应用及进展[J].安徽医药,2008,12(11):1087-1091.
[12] Lander B Z,Alejandro B. A Novel Liquid Chromatography-Mass Spectrometric Method for the Simultaneous Determination of Trimethylamine,Dimethylamine and Methylamine in Fishery Products[J]. Food Chem,2016,196,1207-1214.
[13]朱欣瑶,赛永竹,张晓静,等.实验室中有害气体苯、甲苯、甲醇和丙酮的检测分析[J].中国中医药现代远程教育,2013,11(4):157-160.
[14]李涛,胡青大,唐冬宝.新型C[6]/Si O2/CdTe NPs荧光探针对乙二胺的识别和检测[J].化工管理,2015(16):184-185.
[15]姑力米热·吐尔地,帕提曼·尼扎木丁,燕音,等.四苯基卟啉薄膜/K+交换玻璃光波导传感器的研制及其气敏性研究[J].传感技术学报,2016,29(7):966-970.
[16]王佳明,姑力米热·吐尔地,燕音,等.基于四苯基卟啉铁敏感膜的玻璃光波导传感器对乙二胺的响应特性[J].应用化学,2017,34(7):847-854.
[17] Rakow N A,Suslick K S. A Colorimetric Sensor Array for Odour Visualization[J]. Nature,2000,406(6797):710.
[18] Capan 6)I,Erdoˇgan M,Stanciu G A,et al. The Interaction between the Gas Sensing and Surface Morphology Properties of LB Thin Films of Porphyrins in Terms of the Adsorption Kinetics[J]. Materials Chemistry&Physics,2012,136(2-3):1130-1136.
[19] Nizamidin P,Yimit A,Itoh K. Synthesis and Optical-Electrochemical Gas Sensing Application of Ni-Doped Li Fe PO4Nano-Particle[J]. New Journal of Chemistry,2016,40(1):295-301.
[20] YASIN,Patime,YIMIT,et al. Cyclodextrin Polymer Films Optical Waveguide Sensor for Volatile Organic Gas Detection[J].Chemical Resarch in Chinese University,2012,28(4):682-685.
[21]侯长军,刘琛,霍丹群,等.四苯基卟啉铟纳米材料的制备及其光学传感性能研究[J].功能材料,2011,42(6):1155-1158.
[22] Ghosh A,Selvamani T,Jose D A,et al. Generation of Nanostructures by the Aggregation of Porphyrin Derivatives with Long Alkane Chain in Mix-Solvent[J]. Journal of Nanomaterials,2007(1):1-8.
[23] Nizamidin P,Yimit A,Wang J D,et al. Optical Properties and Sensing Applications of Lithium Iron Phosphate Thin Films[J].Thin Solid Films,2012,520(19):6250-6255.
[24] Janzen M C,Ponder J B,Bailey D P,et al. Colorimetric Sensor Arrays for Volatile Organic Compounds[J]. Analytical Chemistry,2006,78(11):3591-3600.
[25] Askim J R,Mahmoudi M,Suslick K S. Chem Inform Abstract:Optical Sensor Arrays for Chemical Sensing:The Optoelectronic Nose[J].Chemical Society Reviews,2013,42(22):8649-8682.
[26] Abdelhamid R F,Obara Y,Uchida Y,et al. Pi-Pi Interaction between Aromatic Ring and Copper-Coordinated Imidazole Regulates the Blue Copper Active-Site Structure[J]. Journal of Biological Inorganic Chemistry,2007,12(2):165-173.
[27]杨菁菁,刘俊刁. SnO2薄膜的电学气敏特性与光学气敏特性研究[J].化学传感器,1999(2):32-35.
[28] Gouterman M. Spectra of Porphyrins[J]. Journal of Molecular Spectroscpy,1961,6,138-163.
[29] Nú1ez-Nieto X,Solla M,Gómez-Pérez P,et al. Signal-to-Noise Ratio Dependence on Ground Penetrating Radar Antenna Frequency in the Field of Landmine and UXO Detection[J].Measurement,2015,73:24-32.