矿物基载体功能材料调温调湿性能研究进展
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摘要
建筑热湿环境是影响室内人员健康的重要因素,利用无机矿物材料自身的被动调节能力可研制成调温调湿双功能型材料。通过对非金属矿物材料的热物性、微孔结构特征及物质结构稳定性分析,论证矿物材料作为调温控湿材料载体的可行性。介绍多种矿物材料的形貌特点、改性方法及分析国内外多孔型矿物材料在调温和控湿单方面的应用情况,在此基础上综述了现有少数研究的调温调湿双功能材料的制备工艺及热湿综合性能评价指标。认为未来的研究在优化复合材料制备工艺的同时,应当考虑其温度和湿度的响应速度、材料可重复使用性及多指标衡量热湿综合性能。
The thermal and wet environment of building is an important factor affecting the health of indoor people.The passive adjustment ability of inorganic mineral materials can be used to develop a dual-function material with temperature-regulating and humidity-regulating.Through the analysis of the thermal properties,microporous structure characteristics and material structure stability of non-metallic mineral materials,the feasibility of mineral materials as a carrier for temperature-regulating and humidity-regulating materials is demonstrated.This paper introduces the morphological characteristics,modification methods and analyzes the application of porous mineral materials at home and abroad in the aspects of temperature-regulating and humidity-regulating.On this basis,a few existing studies about the preparation process of thermoregulation and dual-function materials and the evaluation index of thermal and wet performance are reviewed.It is concluded that the future research should take into account the response rate of temperature and humidity,the reusability of materials and the multi-index measurement of thermal and wet comprehensive performance while optimizing the preparation process of composite materials.
The thermal and wet environment of building is an important factor affecting the health of indoor people.The passive adjustment ability of inorganic mineral materials can be used to develop a dual-function material with temperature-regulating and humidity-regulating.Through the analysis of the thermal properties,microporous structure characteristics and material structure stability of non-metallic mineral materials,the feasibility of mineral materials as a carrier for temperature-regulating and humidity-regulating materials is demonstrated.This paper introduces the morphological characteristics,modification methods and analyzes the application of porous mineral materials at home and abroad in the aspects of temperature-regulating and humidity-regulating.On this basis,a few existing studies about the preparation process of thermoregulation and dual-function materials and the evaluation index of thermal and wet performance are reviewed.It is concluded that the future research should take into account the response rate of temperature and humidity,the reusability of materials and the multi-index measurement of thermal and wet comprehensive performance while optimizing the preparation process of composite materials.
引文
[1] 胡志波.硅藻土及复合材料结构和表面特性与调湿性能研究[D].北京:中国矿业大学(北京),2017.
[2] 张奕,张小松.有机相变材料储能的研究和进展[J].太阳能学报,2006,27(7):725-730.
[3] 李传常,罗杰,江杰云.基于矿物特性的太阳能储热材料研究进展[J].中国材料进展,2012,31(10):51-56.
[4] 张东.多孔矿物介质对有机相变材料导热性能的影响[J].矿物岩石,2007,27(3):12-16.
[5] 翟天尧,李廷贤,仵斯,等.高导热膨胀石墨/硬脂酸定形相变储能复合材料的制备及储/放热特性[J].科学通报,2018,63(7):674-683.
[6] 张毅,张菁燕,黄斌,等.脂肪酸相变材料导热系数测试及相变传热过程的数值模拟[J].功能材料,2012,43(14):1950-1955.
[7] Han Lei,Li Faliang,Deng Xiangong,et al.Foam-gelcasting preparation,microstructure and thermal insulation performance of porous diatomite ceramics with hierarchical pore structures[J].Journal of the European Ceramic Society,2017,31(7):2717-2725.
[8] Huang Xiang,Alva Guruprasad,Liu Lingkun,et al.Preparation,characterization and thermal properties of fatty acid eutectics/bentonite/expanded graphite composites as novel form-stable thermal energy storage materials[J].Solar Energy Materials and Solar Cells,2017,166:157-166.
[9] Maria Aivalioti,Panagiotis Papoulias,Athanasia Kousaiti,et al.Adsorption of BTEX,MTBE and TAME on natural and modified diatomite[J].Journal of Hazardous Materials,2012,207/208:117-127.
[10] 曲月华,王一凌,亢德华,等.X射线荧光光谱法测定膨润土中主次成分[J].冶金分析,2009,29(10):13-16.
[11] 温淑瑶,马占青,马毅杰.酸活化对膨润土比表面积和孔径的影响研究[J].实验技术与管理,2011,28(10):44-46.
[12] Xie Yue,Li Jun,Lu Zhongyuan,et al.Effects of bentonite slurry on air-void structure and properties of foamed concrete[J].Construction and Building Materials,2018,179(10):207-219.
[13] Bruno J B Silva,Lenivaldo V de Sousa,Paulo H L Quintela,et al.Preparation of ZSM-22 zeolite with hierarchical pore structure[J].Materials Letters,2018,218:119-122.
[14] 王萌,房春生,颜昌宙,等.沸石的改性及其对氨氮吸附特征[J].环境科学研究,2012,25(9):1024-1029.
[15] 冀志江,侯国艳,王静,等.多孔结构无机材料比表面积和孔径分布对调湿性的影响[J].岩石矿物学杂志,2009,28(6):653-660.
[16] 方萍,吴懿,龚光彩.多孔矿物调湿材料的微观结构与其吸湿性能[J].材料导报,2009,23(14):475-477.
[17] 王吉会,王志伟.复合调湿材料的研究进展[J].材料导报,2007,21(6):55-58.
[18] 佟钰,马秀梅,张君男,等.焙烧处理对硅藻土吸/放湿性能的影响[J].硅酸盐通报,2016,35(7):2204-2209.
[19] 陈昭平,罗来涛,李永绣,等.酸处理对海泡石表面及其结构性质的影响[J].南昌大学学报,2000,24(3):68-72.
[20] Wang Fei,Liang Jinsheng,Tang Qingguo,et al.Microstructure of sepiolite and its adsorbing properties to dodecanol[J].Transactions of Nonferrous Metals Society of China,2006,16:406-410.
[21] 项国圣,徐永福,谢胜华,等.盐溶液对膨润土微观结构的影响[J].东南大学学报:自然科学版,2016,43:230-234.
[22] 李门楼.改性硅藻土处理含锌电镀废水的研究[J].湖南科技大学学报:自然科学版,2004,19(3):81-83.
[23] 杨盛春,张译文,贺洁,等.有机插层膨润土的制备及吸附性能研究[J].化工科技,2014,22(4):21-24.
[24] Qian Y,Lindsay C I,Macosko C,et al.Synthesis and properties of vermiculite-reinforced polyurethane nanocomposites[J].ACS Applied Materials & Interfaces,2011,3(9):3709-3717.
[25] 白涛,宋岩,佟钰.一种硅藻土基多功能建筑板材[J].硅酸盐通报,2015,34(10):2743-2747.
[26] 王东旭.脂肪酸/硅藻土定形相变材料的制备及建筑节能应用研究[D].锦州:辽宁工业大学,2017.
[27] Ahmet Sar?.Thermal energy storage characteristics of bentonite-based composite PCMs with enhanced thermal conductivity as novel thermal storage building materials[J].Energy Conversion and Management,2016,117:132-141.
[28] 吕荣超.海泡石、硅藻土、沸石作为调湿建筑材料的基础研究[D].北京:中国建筑材料科学研究院,2005.
[29] Zhang D,Zhou J,Wu K,et al.Granular phase changing composites for thermal energy storage[J].Solar Energy,2005,78(3):471-480.
[30] 管学茂,宋纤纤,张建武,等.膨润土相变储能材料的制备与性能研究[J].太阳能学报,2015,36(4):950-954.
[31] 王小鹏,张毅,沈振球,等.熔融插层法制备蒙脱石基石蜡复合相变储能材料[J].硅酸盐学报,2011,39(4):624-629.
[32] Su-Gwang Jeong,Jisoo Jeon,Jeong-Hun Lee,et al.Optimal preparation of PCM/diatomite composites for enhancing thermal properties[J].International Journal of Heat and Mass Transfer,2016,62:711-717.
[33] 钱婷婷.硅藻土基定形复合相变储能材料的制备与性能研究[D].北京:中国地质大学(北京),2017.
[34] 蒋达华,周阳,罗凯.海泡石复合相变储能建筑材料的试验研究[J].非金属矿,2008,31(4):4-5.
[35] Shen Qiang,Ouyang Jing,Zhang Yi,et al.Lauric acid/modified sepiolite composite as a form-stable phase change material for thermal energy storage[J].Applied Clay Science,2017,146:14-22.
[36] 刘弋潞,王春燕,宿旭昊,等.硬脂酸/钠基有机膨润土相变储能石膏板的性能研究[J].化工新型材料,2015,43(6):222-224,227.
[37] Chen Changzhong,Liu Xiaodi,Liu Wenmin,et al.A comparative study of myristic acid/bentonite and myristic acid/Eudragit L100 form stable phase change materials for thermal energy storage[J].Solar Energy Materials and Solar Cells,2014,127:14-20.
[38] 王汉青,杨荣郭,王正祥,等.海泡石用于调湿涂料的吸湿性能改性研究[J].建筑热能通风空调,2013,32(3):9-13.
[39] 刘露.氧化镁基调湿材料的研究与应用[D].合肥:安徽建筑大学,2016.
[40] 黄剑锋,曹丽云.膨润土/PAM插层复合调湿膜的性能[J].膜科学与技术,2004(2):19-22.
[41] 任曙凭.无机矿物/聚丙烯酸(钠)复合材料的制备与调湿性能[D].天津:天津大学,2012.
[42] 马明明,张伟.硅藻土基调湿建筑材料的制备与表征[J].新型建筑材料,2017,44(12):86-88,93.
[43] 尚建丽,倪勃.海泡石相变材料的制备及热湿性能的试验研究[J].非金属矿,2014,37(3):5-7,11.
[44] 尚建丽,张浩.癸酸-棕榈酸/SiO2相变储湿复合材料的制备与表征[J].复合材料学报,2016,33(2):341-349.
[45] 尚建丽,麻向龙,张磊,等.多孔载体相变材料的热湿综合性能[J].浙江大学学报:工学版,2016,50(5):879-886.
[46] 尚建丽,田野,宗志芳.改性蒙脱土定型复合材料及热湿性能实验[J].硅酸盐通报,2016,35(12):4184-4190.
[47] 张浩,黄新杰,宗志芳,等.基于热湿综合性能的棕榈醇-棕榈酸-月桂酸/SiO2复合材料制备方案的响应面法优化[J].复合材料学报,2017,34(1):203-209.
[48] 尚建丽,张浩,熊磊,等.基于均匀设计优化制备癸酸-棕榈酸/SiO2复合相变材料[J].材料工程,2015,43(9):94-102.
[49] 宗志芳,陈德鹏,卜双双.基于FTIR和RBF网络的二元脂肪酸/SiO2相变储湿复合材料热湿性能优选预测[J].复合材料学报,2018,35(8):2246-2251.
[2] 张奕,张小松.有机相变材料储能的研究和进展[J].太阳能学报,2006,27(7):725-730.
[3] 李传常,罗杰,江杰云.基于矿物特性的太阳能储热材料研究进展[J].中国材料进展,2012,31(10):51-56.
[4] 张东.多孔矿物介质对有机相变材料导热性能的影响[J].矿物岩石,2007,27(3):12-16.
[5] 翟天尧,李廷贤,仵斯,等.高导热膨胀石墨/硬脂酸定形相变储能复合材料的制备及储/放热特性[J].科学通报,2018,63(7):674-683.
[6] 张毅,张菁燕,黄斌,等.脂肪酸相变材料导热系数测试及相变传热过程的数值模拟[J].功能材料,2012,43(14):1950-1955.
[7] Han Lei,Li Faliang,Deng Xiangong,et al.Foam-gelcasting preparation,microstructure and thermal insulation performance of porous diatomite ceramics with hierarchical pore structures[J].Journal of the European Ceramic Society,2017,31(7):2717-2725.
[8] Huang Xiang,Alva Guruprasad,Liu Lingkun,et al.Preparation,characterization and thermal properties of fatty acid eutectics/bentonite/expanded graphite composites as novel form-stable thermal energy storage materials[J].Solar Energy Materials and Solar Cells,2017,166:157-166.
[9] Maria Aivalioti,Panagiotis Papoulias,Athanasia Kousaiti,et al.Adsorption of BTEX,MTBE and TAME on natural and modified diatomite[J].Journal of Hazardous Materials,2012,207/208:117-127.
[10] 曲月华,王一凌,亢德华,等.X射线荧光光谱法测定膨润土中主次成分[J].冶金分析,2009,29(10):13-16.
[11] 温淑瑶,马占青,马毅杰.酸活化对膨润土比表面积和孔径的影响研究[J].实验技术与管理,2011,28(10):44-46.
[12] Xie Yue,Li Jun,Lu Zhongyuan,et al.Effects of bentonite slurry on air-void structure and properties of foamed concrete[J].Construction and Building Materials,2018,179(10):207-219.
[13] Bruno J B Silva,Lenivaldo V de Sousa,Paulo H L Quintela,et al.Preparation of ZSM-22 zeolite with hierarchical pore structure[J].Materials Letters,2018,218:119-122.
[14] 王萌,房春生,颜昌宙,等.沸石的改性及其对氨氮吸附特征[J].环境科学研究,2012,25(9):1024-1029.
[15] 冀志江,侯国艳,王静,等.多孔结构无机材料比表面积和孔径分布对调湿性的影响[J].岩石矿物学杂志,2009,28(6):653-660.
[16] 方萍,吴懿,龚光彩.多孔矿物调湿材料的微观结构与其吸湿性能[J].材料导报,2009,23(14):475-477.
[17] 王吉会,王志伟.复合调湿材料的研究进展[J].材料导报,2007,21(6):55-58.
[18] 佟钰,马秀梅,张君男,等.焙烧处理对硅藻土吸/放湿性能的影响[J].硅酸盐通报,2016,35(7):2204-2209.
[19] 陈昭平,罗来涛,李永绣,等.酸处理对海泡石表面及其结构性质的影响[J].南昌大学学报,2000,24(3):68-72.
[20] Wang Fei,Liang Jinsheng,Tang Qingguo,et al.Microstructure of sepiolite and its adsorbing properties to dodecanol[J].Transactions of Nonferrous Metals Society of China,2006,16:406-410.
[21] 项国圣,徐永福,谢胜华,等.盐溶液对膨润土微观结构的影响[J].东南大学学报:自然科学版,2016,43:230-234.
[22] 李门楼.改性硅藻土处理含锌电镀废水的研究[J].湖南科技大学学报:自然科学版,2004,19(3):81-83.
[23] 杨盛春,张译文,贺洁,等.有机插层膨润土的制备及吸附性能研究[J].化工科技,2014,22(4):21-24.
[24] Qian Y,Lindsay C I,Macosko C,et al.Synthesis and properties of vermiculite-reinforced polyurethane nanocomposites[J].ACS Applied Materials & Interfaces,2011,3(9):3709-3717.
[25] 白涛,宋岩,佟钰.一种硅藻土基多功能建筑板材[J].硅酸盐通报,2015,34(10):2743-2747.
[26] 王东旭.脂肪酸/硅藻土定形相变材料的制备及建筑节能应用研究[D].锦州:辽宁工业大学,2017.
[27] Ahmet Sar?.Thermal energy storage characteristics of bentonite-based composite PCMs with enhanced thermal conductivity as novel thermal storage building materials[J].Energy Conversion and Management,2016,117:132-141.
[28] 吕荣超.海泡石、硅藻土、沸石作为调湿建筑材料的基础研究[D].北京:中国建筑材料科学研究院,2005.
[29] Zhang D,Zhou J,Wu K,et al.Granular phase changing composites for thermal energy storage[J].Solar Energy,2005,78(3):471-480.
[30] 管学茂,宋纤纤,张建武,等.膨润土相变储能材料的制备与性能研究[J].太阳能学报,2015,36(4):950-954.
[31] 王小鹏,张毅,沈振球,等.熔融插层法制备蒙脱石基石蜡复合相变储能材料[J].硅酸盐学报,2011,39(4):624-629.
[32] Su-Gwang Jeong,Jisoo Jeon,Jeong-Hun Lee,et al.Optimal preparation of PCM/diatomite composites for enhancing thermal properties[J].International Journal of Heat and Mass Transfer,2016,62:711-717.
[33] 钱婷婷.硅藻土基定形复合相变储能材料的制备与性能研究[D].北京:中国地质大学(北京),2017.
[34] 蒋达华,周阳,罗凯.海泡石复合相变储能建筑材料的试验研究[J].非金属矿,2008,31(4):4-5.
[35] Shen Qiang,Ouyang Jing,Zhang Yi,et al.Lauric acid/modified sepiolite composite as a form-stable phase change material for thermal energy storage[J].Applied Clay Science,2017,146:14-22.
[36] 刘弋潞,王春燕,宿旭昊,等.硬脂酸/钠基有机膨润土相变储能石膏板的性能研究[J].化工新型材料,2015,43(6):222-224,227.
[37] Chen Changzhong,Liu Xiaodi,Liu Wenmin,et al.A comparative study of myristic acid/bentonite and myristic acid/Eudragit L100 form stable phase change materials for thermal energy storage[J].Solar Energy Materials and Solar Cells,2014,127:14-20.
[38] 王汉青,杨荣郭,王正祥,等.海泡石用于调湿涂料的吸湿性能改性研究[J].建筑热能通风空调,2013,32(3):9-13.
[39] 刘露.氧化镁基调湿材料的研究与应用[D].合肥:安徽建筑大学,2016.
[40] 黄剑锋,曹丽云.膨润土/PAM插层复合调湿膜的性能[J].膜科学与技术,2004(2):19-22.
[41] 任曙凭.无机矿物/聚丙烯酸(钠)复合材料的制备与调湿性能[D].天津:天津大学,2012.
[42] 马明明,张伟.硅藻土基调湿建筑材料的制备与表征[J].新型建筑材料,2017,44(12):86-88,93.
[43] 尚建丽,倪勃.海泡石相变材料的制备及热湿性能的试验研究[J].非金属矿,2014,37(3):5-7,11.
[44] 尚建丽,张浩.癸酸-棕榈酸/SiO2相变储湿复合材料的制备与表征[J].复合材料学报,2016,33(2):341-349.
[45] 尚建丽,麻向龙,张磊,等.多孔载体相变材料的热湿综合性能[J].浙江大学学报:工学版,2016,50(5):879-886.
[46] 尚建丽,田野,宗志芳.改性蒙脱土定型复合材料及热湿性能实验[J].硅酸盐通报,2016,35(12):4184-4190.
[47] 张浩,黄新杰,宗志芳,等.基于热湿综合性能的棕榈醇-棕榈酸-月桂酸/SiO2复合材料制备方案的响应面法优化[J].复合材料学报,2017,34(1):203-209.
[48] 尚建丽,张浩,熊磊,等.基于均匀设计优化制备癸酸-棕榈酸/SiO2复合相变材料[J].材料工程,2015,43(9):94-102.
[49] 宗志芳,陈德鹏,卜双双.基于FTIR和RBF网络的二元脂肪酸/SiO2相变储湿复合材料热湿性能优选预测[J].复合材料学报,2018,35(8):2246-2251.