石墨烯增强增韧非氧化物陶瓷的研究进展
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摘要
由于在非氧化物陶瓷基体中引入石墨烯可通过裂纹偏转及桥接等多种增韧机制来提高其强度和断裂韧性,因此综述了石墨烯增强增韧非氧化物陶瓷(例如:硼化物陶瓷、氮化物陶瓷、碳化物陶瓷等)的研究现状,总结了石墨烯在非氧化物陶瓷中的增韧机制,提出了该复合陶瓷存在的缺点,并指出了其发展方向。
The research progress of graphene reinforced and toughened non-oxide ceramics( such as boride ceramics,nitride ceramics,carbide ceramics) was reviewed. Adding graphene can improve the strength and fracture toughness of non-oxide ceramics by crack deflection and bridging mechanisms. The toughening mechanism of graphene in non-oxide ceramics was summarized,the shortcomings of the composite ceramics were pointed out,and the development trend was put forward.
The research progress of graphene reinforced and toughened non-oxide ceramics( such as boride ceramics,nitride ceramics,carbide ceramics) was reviewed. Adding graphene can improve the strength and fracture toughness of non-oxide ceramics by crack deflection and bridging mechanisms. The toughening mechanism of graphene in non-oxide ceramics was summarized,the shortcomings of the composite ceramics were pointed out,and the development trend was put forward.
引文
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[3]NEUMAN E W,HILMAS G E,FAHRENHOLTZ W G.Mechanical behavior of zirconium diboride-silicon carbide-boron carbide ceramics up to 2200℃[J].J Eur Ceram Soc,2015,35(2):463-476.
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[17]JIANG K,LI J,LIU J.Spark plasma sintering and characterization of graphene platelet/ceramic composites[J].Adv Eng Mater,2015,17(5):716-722.
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[19]BODIS E,CORA I,BALAZSI C,et al.Spark plasma sintering of graphene reinforced silicon carbide ceramics[J].Ceram Int,2017,43(12):9005-9011.
[20]XIA H,ZHANG X,SHI Z,et al.Mechanical and thermal properties of reduced graphene oxide reinforced aluminum nitride ceramic composites[J].Mater Sci Eng A,2015,639(7):29-36.
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[25]YADHUKULAKRISHNAN G B,KARUMURI S,RAHMAN A,et al.Spark plasma sintering of graphene reinforced zirconium diboride ultra-high temperature ceramic composites[J].Ceram Int,2013,39(6):6637-6646.
[26]ASL M S,KAKROUDI M G.Characterization of hot-pressed graphene reinforced Zr B2-SiC composite[J].Mater Sci Eng A,2015,625(2):385-392.
[27]ZHI W,HONG C,ZHANG X,et al.Microstructure and thermal shock behavior of Zr B2-SiC-graphite composite[J].Mater Chem Phy,2009,113(1):338-341.
[28]AN Y M,ZHANG X H,HAN W B,et al.Interface of Graphene/Zr B2ceramics structure by molecular dynamics simulation[J].Key Eng Mater,2015,655:82-86.
[29]SCHWARZ M,MIEHE G,ZERR A,et al.Spinel-Si3N4:Multi-anvil press synthesis and structural refinement[J].Adv Mater,2000,12(12):883-887.
[30]LANGE F F.Fracture toughness of Si3N4 as a function of the initialα-phase content[J].J Am Ceram Soc,2010,62(7-8):428-430.
[31]RILEY F L.Silicon nitride and related materials[J].J Am Ceram Soc,2000,83(2):245-265.
[32]SANDERS W A,GROSECLOSE L E.Flexural stress rupture and creep of selected commercial silicon nitrides[J].J Am Ceram Soc,1993,76(2):553-556.
[33]WALKER L S,MAROTTO V R,RAFIEE M A,et al.Toughening in graphene ceramic composites[J].ACS Nano,2011,5(4):3182-3190.
[34]ZENG Q F,YONG-DONG X U,ZHANG L T,et al.Characterization of microstructure and mechanical properties of in-situ toughened Si3N4[J].J Inorg Mater,2000,17(1):105-110.
[35]陈力,冯坚,李永清,等.烧结助剂对自增韧Si3N4陶瓷显微结构和性能的影响[J].硅酸盐学报,2003,31(4):382-385.
[36]DUSZA J,MORGIEL J,DUSZOVA A,et al.Microstructure and fracture toughness of Si3N4+graphene platelet composites[J].JEur Ceram Soc,2012,32(12):3389-3397.
[37]KUN P,TAPASZTO O,WEBER F,et al.Determination of structural and mechanical properties of multilayer graphene added silicon nitride-based composites[J].Ceram Int,2012,38(1):211-216.
[38]YANG Y,LI B,ZHANG C,et al.Fabrication and properties of graphene reinforced silicon nitride composite materials[J].Mater Sci Eng A,2015,644(9):90-95.
[39]MASHHADI H A,WADA N,TOMOSHIGE R,et al.Fabrication of bulk Al N-TiN nanocomposite by reactive ball milling and underwater shock consolidation technique[J].Ceram Int,2011,37(6):1747-1754.
[40]STRITE S,MORKOC H.Gan,Al N and InN:a review[J].J Vac Sci Technol B,1992,10(4):1237-1266.
[41]李友芬,刘伟伟,张麟宁.Al N陶瓷烧结技术研究进展[J].现代技术陶瓷,2006,27(1):28-31.
[42]秦明礼,曲选辉,林健凉,等.氮化铝陶瓷研究和发展[J].稀有金属材料与工程,2002,31(1):8-12.
[43]SHON I J.Enhanced mechanical properties of the nanostructured Al N-graphene composites rapidly sintered by high-frequency induction heating[J].Mater Sci Eng A,2016,42(14):1636-1642.
[44]CHENG L,XIE Z,LIU G.Spark plasma sintering of Ti C ceramic with tungsten carbide as a sintering additive[J].J Eur Ceram Soc,2013,33(15-16):2971-2977.
[45]尹月,马北越.碳化物及碳化硅基复合粉体制备的新进展[J].耐火材料,2016,50(1):69-74+80.
[46]NUNEZ-GONZALEZ B,ORTIZ A L,GUIBERTEAU F,et al.Improvement of the spark-plasma-sintering kinetics of Zr C by highenergy ball-milling[J].J Am Ceram Soc,2012,95(2):453-456.
[47]JIANG Q C,LI X L,WANG H Y.Fabrication of TiC particulate reinforced magnesium matrix composites[J].Scripta Mater,2003,48(6):713-717.
[48]LI Q S,ZHANG Y J,GONG H Y,et al.Enhanced fracture toughness of pressureless-sintered SiC ceramics by addition of graphene[J].J Mater Sci Tech,2016,32(7):633-638.
[49]BELMONTE M,NISTAL A,BOUTBIEN P,et al.Toughened and strengthened silicon carbide ceramics by adding graphene-based fillers[J].Scripta Mater,2016,113(3):127-130.
[50]LI J L,WANG L J,BAI G Z,et al.Microstructure and mechanical properties of in situ produced Ti C/C nanocomposite by spark plasma sintering[J].Scripta Mater,2005,52(9):867-871.
[51]CHENG Y,ZHANG Y,WAN T,et al.Mechanical properties and toughening mechanisms of graphene platelets reinforced Al2O3/Ti Ccomposite ceramic tool materials by microwave sintering[J].Mater Sci Eng A,2016,680(1):190-196.
[52]SEDLAK R,KOVALCIKOVA A,MU'DRA E,et al.Boron carbide/graphene platelet ceramics with improved fracture toughness and electrical conductivity[J].J Eur Ceram Soc,2017,37(12):3773-3780.
[2]LOW I M.Ceramic matrix composites:microstructure,properties and applications[M].England:Woodhead Publishing,2006:100-103.
[3]NEUMAN E W,HILMAS G E,FAHRENHOLTZ W G.Mechanical behavior of zirconium diboride-silicon carbide-boron carbide ceramics up to 2200℃[J].J Eur Ceram Soc,2015,35(2):463-476.
[4]ZHANG J X,JIANG D L,LIN Q L,et al.Properties of silicon carbide ceramics from gelcasting and pressureless sintering[J].Mater Design,2015,65(20):12-16.
[5]IGHODARO O L,OKOLI O I.Fracture toughness enhancement for alumina systems:A review[J].Int J Appl Ceram Tech,2008,5(3):313-323.
[6]曲远方.现代陶瓷材料及技术[M].上海:华东理工大学出版社,2008:452-487.
[7]ZELLER F,MüLLER C,MIRANZO P,et al.Exceptional micromachining performance of silicon carbide ceramics by adding graphene nanoplatelets[J].J Eur Ceram Soc,2017,37(12):3813-3821.
[8]罗明,李亚伟,金胜利,等.碳纳米管增强陶瓷基复合材料的研究与展望[J].材料导报,2010,24(S1):155-158.
[9]SHA J J,LI J,LV Z Z,et al.Zr B2-based composites toughened by as-received and heat-treated short carbon fibers[J].J Eur Ceram Soc,2016,37(2):549-558.
[10]SHA J J,WEI Z Q,LI J,et al.Mechanical properties and toughening mechanism of WC-doped Zr B2-Zr Si2ceramic composites by hot pressing[J].Mater Design,2014,62(10):199-204.
[11]RAMIREZ C,MIRANZO P,BELMONTE M,et al.Extraordinary toughening enhancement and flexural strength in Si3N4composites using graphene sheets[J].J Eur Ceram Soc,2014,34(2):161-169.
[12]李旭,赵卫峰,陈国华.石墨烯的制备与表征研究[J].材料导报,2008,22(8):48-52.
[13]傅强,包信和.石墨烯的化学研究进展[J].科学通报,2009,54(18):2657-2666.
[14]GEIM A K,KIM P.Carbon wonderland[J].Sci Am,2008,298(4):90-97.
[15]GEIM A K,NOVOSELOV K S.The rise of graphene[J].Nat Mater,2007,6(3):183-191.
[16]ZHAN J M,YAO X H,LI W H,et al.Tensile mechanical properties study of Si C/graphene composites based on molecular dynamics[J].Comp Mater Sci,2017,131:266-274.
[17]JIANG K,LI J,LIU J.Spark plasma sintering and characterization of graphene platelet/ceramic composites[J].Adv Eng Mater,2015,17(5):716-722.
[18]HUSSAINOVA I,DROZDOVA M,AGHAYAN M,et al.Graphene covered alumina nanofibers as toughening agent in alumina ceramics[J].Adv Sci Tech,2014,88(88):49-53.
[19]BODIS E,CORA I,BALAZSI C,et al.Spark plasma sintering of graphene reinforced silicon carbide ceramics[J].Ceram Int,2017,43(12):9005-9011.
[20]XIA H,ZHANG X,SHI Z,et al.Mechanical and thermal properties of reduced graphene oxide reinforced aluminum nitride ceramic composites[J].Mater Sci Eng A,2015,639(7):29-36.
[21]ZUO F J,CHENG L F,XIANG L Y,et al.Ablative property of laminated Zr B2-SiC ceramics under oxyacetylence torch[J].Ceram Int,2013,39(4):4627-4631.
[22]MALLIK M,KAILATH A J,RAY K K,et al.Electrical and thermophysical properties of Zr B2and Hf B2based composites[J].J Eur Ceram Soc,2012,32(10):2545-2555.
[23]张国军,邹冀,倪德伟,等.硼化物陶瓷:烧结致密化、微结构调控与性能提升[J].无机材料学报,2012,27(3):225-233.
[24]MONTEVERDE F,BELLOSI A,SCATTEIA L.Processing and properties of ultra-high temperature ceramics for space applications[J].Mater Sci Eng A,2008,485(1):415-421.
[25]YADHUKULAKRISHNAN G B,KARUMURI S,RAHMAN A,et al.Spark plasma sintering of graphene reinforced zirconium diboride ultra-high temperature ceramic composites[J].Ceram Int,2013,39(6):6637-6646.
[26]ASL M S,KAKROUDI M G.Characterization of hot-pressed graphene reinforced Zr B2-SiC composite[J].Mater Sci Eng A,2015,625(2):385-392.
[27]ZHI W,HONG C,ZHANG X,et al.Microstructure and thermal shock behavior of Zr B2-SiC-graphite composite[J].Mater Chem Phy,2009,113(1):338-341.
[28]AN Y M,ZHANG X H,HAN W B,et al.Interface of Graphene/Zr B2ceramics structure by molecular dynamics simulation[J].Key Eng Mater,2015,655:82-86.
[29]SCHWARZ M,MIEHE G,ZERR A,et al.Spinel-Si3N4:Multi-anvil press synthesis and structural refinement[J].Adv Mater,2000,12(12):883-887.
[30]LANGE F F.Fracture toughness of Si3N4 as a function of the initialα-phase content[J].J Am Ceram Soc,2010,62(7-8):428-430.
[31]RILEY F L.Silicon nitride and related materials[J].J Am Ceram Soc,2000,83(2):245-265.
[32]SANDERS W A,GROSECLOSE L E.Flexural stress rupture and creep of selected commercial silicon nitrides[J].J Am Ceram Soc,1993,76(2):553-556.
[33]WALKER L S,MAROTTO V R,RAFIEE M A,et al.Toughening in graphene ceramic composites[J].ACS Nano,2011,5(4):3182-3190.
[34]ZENG Q F,YONG-DONG X U,ZHANG L T,et al.Characterization of microstructure and mechanical properties of in-situ toughened Si3N4[J].J Inorg Mater,2000,17(1):105-110.
[35]陈力,冯坚,李永清,等.烧结助剂对自增韧Si3N4陶瓷显微结构和性能的影响[J].硅酸盐学报,2003,31(4):382-385.
[36]DUSZA J,MORGIEL J,DUSZOVA A,et al.Microstructure and fracture toughness of Si3N4+graphene platelet composites[J].JEur Ceram Soc,2012,32(12):3389-3397.
[37]KUN P,TAPASZTO O,WEBER F,et al.Determination of structural and mechanical properties of multilayer graphene added silicon nitride-based composites[J].Ceram Int,2012,38(1):211-216.
[38]YANG Y,LI B,ZHANG C,et al.Fabrication and properties of graphene reinforced silicon nitride composite materials[J].Mater Sci Eng A,2015,644(9):90-95.
[39]MASHHADI H A,WADA N,TOMOSHIGE R,et al.Fabrication of bulk Al N-TiN nanocomposite by reactive ball milling and underwater shock consolidation technique[J].Ceram Int,2011,37(6):1747-1754.
[40]STRITE S,MORKOC H.Gan,Al N and InN:a review[J].J Vac Sci Technol B,1992,10(4):1237-1266.
[41]李友芬,刘伟伟,张麟宁.Al N陶瓷烧结技术研究进展[J].现代技术陶瓷,2006,27(1):28-31.
[42]秦明礼,曲选辉,林健凉,等.氮化铝陶瓷研究和发展[J].稀有金属材料与工程,2002,31(1):8-12.
[43]SHON I J.Enhanced mechanical properties of the nanostructured Al N-graphene composites rapidly sintered by high-frequency induction heating[J].Mater Sci Eng A,2016,42(14):1636-1642.
[44]CHENG L,XIE Z,LIU G.Spark plasma sintering of Ti C ceramic with tungsten carbide as a sintering additive[J].J Eur Ceram Soc,2013,33(15-16):2971-2977.
[45]尹月,马北越.碳化物及碳化硅基复合粉体制备的新进展[J].耐火材料,2016,50(1):69-74+80.
[46]NUNEZ-GONZALEZ B,ORTIZ A L,GUIBERTEAU F,et al.Improvement of the spark-plasma-sintering kinetics of Zr C by highenergy ball-milling[J].J Am Ceram Soc,2012,95(2):453-456.
[47]JIANG Q C,LI X L,WANG H Y.Fabrication of TiC particulate reinforced magnesium matrix composites[J].Scripta Mater,2003,48(6):713-717.
[48]LI Q S,ZHANG Y J,GONG H Y,et al.Enhanced fracture toughness of pressureless-sintered SiC ceramics by addition of graphene[J].J Mater Sci Tech,2016,32(7):633-638.
[49]BELMONTE M,NISTAL A,BOUTBIEN P,et al.Toughened and strengthened silicon carbide ceramics by adding graphene-based fillers[J].Scripta Mater,2016,113(3):127-130.
[50]LI J L,WANG L J,BAI G Z,et al.Microstructure and mechanical properties of in situ produced Ti C/C nanocomposite by spark plasma sintering[J].Scripta Mater,2005,52(9):867-871.
[51]CHENG Y,ZHANG Y,WAN T,et al.Mechanical properties and toughening mechanisms of graphene platelets reinforced Al2O3/Ti Ccomposite ceramic tool materials by microwave sintering[J].Mater Sci Eng A,2016,680(1):190-196.
[52]SEDLAK R,KOVALCIKOVA A,MU'DRA E,et al.Boron carbide/graphene platelet ceramics with improved fracture toughness and electrical conductivity[J].J Eur Ceram Soc,2017,37(12):3773-3780.