无溶剂绝缘有机硅浸渍树脂研究进展
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摘要
绝缘浸渍树脂是电子电气产品绕组的主要绝缘材料,可提高绝缘结构的介电、导热、机械和防护性能。电机电器设备向大容量、轻量化、智能化的发展以及变压器向高电压、远距离传输的发展,对绝缘树脂的质量、可靠性,特别是耐热性提出了更高的要求。无溶剂绝缘有机硅浸渍树脂相较于其他绝缘浸渍树脂,兼具无机和有机材料特点,综合性能优异,是最具发展前景的耐高温浸渍树脂。首先介绍有机硅浸渍树脂分子结构、特性、分类,重点阐述无溶剂绝缘有机硅浸渍树脂的组成、性能以及应用领域,特别对基础树脂和催化剂的制备技术进行了综述。最后,指出无溶剂绝缘有机硅浸渍树脂目前存在的问题和发展趋势。
Insulation impregnating resin is a kind of important insulation materials of electric and electronic equipment winding,it can improve the dielectric,thermal conductivity,mechanical and protective properties of the insulation system.Along with the high-capacity,lightweight and intelligent development of motor or electrical equipment,as well as the high voltage and long distance transmission development of power transformer,people have put forward a higher requirement for quality and reliability,especially the heat-resistant performance of insulation resin. Comparing with other insulation impregnating resin,solvent-free insulation organosilicon impregnating resin with organic-inorganic hybrid materials characteristics and excellent comprehensive performance,is the most promising heat-resistant insulation impregnating resin. In this review,the molecular structure,peculiarity and classify of insulation organosilicon impregnating resin are firstly introduced,mainly focusing on the composition,properties and application field,especially on the preparation method of solvent-free insulation organosilicon impregnating resin. This review ends with a summary and some perspectives on the challenges and new directions in this exciting and still emerging area of research.
Insulation impregnating resin is a kind of important insulation materials of electric and electronic equipment winding,it can improve the dielectric,thermal conductivity,mechanical and protective properties of the insulation system.Along with the high-capacity,lightweight and intelligent development of motor or electrical equipment,as well as the high voltage and long distance transmission development of power transformer,people have put forward a higher requirement for quality and reliability,especially the heat-resistant performance of insulation resin. Comparing with other insulation impregnating resin,solvent-free insulation organosilicon impregnating resin with organic-inorganic hybrid materials characteristics and excellent comprehensive performance,is the most promising heat-resistant insulation impregnating resin. In this review,the molecular structure,peculiarity and classify of insulation organosilicon impregnating resin are firstly introduced,mainly focusing on the composition,properties and application field,especially on the preparation method of solvent-free insulation organosilicon impregnating resin. This review ends with a summary and some perspectives on the challenges and new directions in this exciting and still emerging area of research.
引文
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[3]Lu Ru(卢儒).China,201310358487.6[P].2013-08-16.
[4]Advanced Materials Institute,Shandong Academy of Science(山东科学院新材料研究所).China,201610525052.X[P].2016-11-23.
[5]Bengbu Triumph Engineering Technology Co.,Ltd.(蚌埠凯盛工程技术有限公司).China,201410065707.0[P].2014-6-25.
[6]Penglai Special Insulating Material Plant(蓬莱市特种绝缘材料厂).China,201510372196.1[P].2015-12-09.
[7]He Nannan(贺楠男),Wang Hualin(王华林),Wang Ming(王明),et al.Paint&Coatings Industry(涂料工业)[J],2011,40(6):39-43.
[8]Zhang Shuling(张淑玲),Luo Huisen(罗慧森),Chen Xingqi(陈行琦).Paint&Coatings Industry(涂料工业)[J],1996,6:10-11.
[9]Zhang Shuling(张淑玲),Chen Xingqi(陈行琦),Sun Zeliang(孙泽良),et al.Surface Technology(表面技术)[J],1992,21(6):291-294.
[10]Zhang Jianhua(张建华),Jiang Qibin(姜其斌),Lin Jinhuo(林金火).Insulating Materials(绝缘材料)[J],2007,40(1):11-13.
[11]Zhang Jianhua(张建华).Dissertation for Master(硕士论文)[D].Fuzhou:Fujian Normal University,2007.
[12]Wang Xuemei(王雪镅),Hao Zhifeng(郝志峰),Yujian(余坚),et al.Chemical Regeants(化学试剂)[J],2009,31(11):903-906.
[13]Meng Jiru(盂季茹),Liang Guozheng(梁国正),Zhao Lei(赵磊),et al.New Chemical Materials(化工新型材料)[J],2000,28(9):33-35.
[14]Liao Xiqiu(廖昔虬),Tang Bozhi(唐博志),Yang Peiling(杨佩铃),et al.China Synthetic Resin and Plastics(合成树脂及塑料)[J],2011,28(2):27-31.
[15]Peng Hualong(彭华龙),You Xiaozi(尤小姿),Xu Xiaoming(徐晓明),et al.Insulating Materials(绝缘材料)[J],2011,44(4):16-19.
[16]Yang Xiongfa(杨雄发),Yang Linlin(杨琳琳),Cao Cheng(曹诚),et al.Chemical Journal of Chinese Universities(高等学校化学学报)[J],2012,33(5):1078-1083.
[17]Ma Kechao(马克超),Jiang Yiqian(姜逸倩),Liu Yanjun(柳艳君),et al.Modern Chemical Industry(现代化工)[J],2013,33(4):91-94.
[18]Jiang Dawei(蒋大伟).Dissertation for Master(硕士论文)[D].Zhuzhou:Hunan University of Technology,2010.
[19]Xiangtan University(湘潭大学).China,201510700363.0[P].2016-01-06.
[20]Fu Junjie(付俊杰),Huang Jian(黄健),Deng Zhihua(邓志华),et al.New Chemical Materials(化工新型材料)[J],2016,44(10):166-167.
[21]Fu Junjie(付俊杰),Huang Jian(黄健),Deng Zhihua(邓志华),et al.New Chemical Materials(化工新型材料)[J],2017,45(2):186-187.
[22]Wang Xiaolu(汪晓璐).Dissertation for Master(硕士论文)[D].Beijing:Beijing University of Chemical Technology,2012.
[23]Zhou Ke(周珂),Luan Yinghao(栾英豪),Ma Xinsheng(马新胜).China Plastics Industry(中国塑料工业)[J],2014,42(3):50-53.
[24]Zhuzhou Times New Material Technology Co.,Ltd.(株洲时代新材料科技股份有限公司).China,201510735510.8[P].2016-02-03.
[25]Zhang Beijing(张北京).Dissertation for Master(硕士论文)[D].Suzhou:Soochow University,2011.
[26]Li Jinhui(李金辉),Li Bing(李冰),Peng Dan(彭丹),et al.Materials Review(材料导报)[J],2017,31(29):309-314.
[27]Huang Wenrun(黄文润).Liquid Silicone Rubber(液体硅橡胶)[M].Chengdu:Sichuan Science and Technology Press,2009:255.
[28]Kato T,Isshiki M.WO,2003035763[P].2003-01-05.
[29]Lai Guoqiao(来国桥),Xing Songmin(幸松民).Organosilicon Products Synthesis Process and Application(有机硅产品合成工艺及应用)[M].Beijing:Chemical Industry Press,2010:652.
[30]Floyd A B,Chi-long L,Myron T.US,3933880[P].1976-01-20.
[31]Fujiki H,Miyoshi K.EP,0916697[P].1999-05-19.
[32]Hara H.JP,1999000336191[P].1999-11-26.
[33]Schuyler B S.US,3923705[P].1975-12-02.
[34]Danishefsky S J,Lewis L N.US,5206329[P].1993-04-27.
[35]Richard P E,Round L.US,4256870[P].1981-03-17.
[36]Richard P E,Round L.US,4347346[P].1982-08-31.
[37]Dauth J,Peetz U,Deubzer B.US,5523436A[P].1996-06-04.
[38]Deng Qingshan(邓青山),Yan Aiguo(颜爱国).Journal of Hunan University of Technology(湖南工业大学学报)[J],2011,25(5):9-13.
[39]Zhong Jinghe(衷敬合),Jiang Qibin(姜其斌),Li Yong(黎勇),et al.Insulating Materials(绝缘材料)[J],2008,41(6):21-24.
[40]Li Bing(李冰),Peng Dan(彭丹),Mou Qiuhong(牟秋红),et al.Shandong Science(山东科学)[J],2016,29(4):44-49.