柴油加氢处理工艺研究进展
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摘要
随着环保法案的日益严格,对柴油质量的要求也在逐步提高。因此,开发一种高效环保的柴油加氢处理工艺显得尤为关键。利用柴油加氢处理技术使劣质柴油馏分得到全面改善,达到低硫、高十六烷值的柴油产品标准。论述了国内外常用的柴油加氢处理技术,及对每种工艺的原理迚行详细阐述,相应地列举了在工业中的应用,幵就今后的发展方向作了说明。
With the increasingly stringent environmental protection, the demand for diesel quality is gradually increasing. Therefore, it is very important to develop an efficient and environmentally friendly diesel hydrotreating process. These technologies are used to improve the fraction of low-grade diesel oil to meet the standard of low sulfur and high sixteen alkane diesel products. In this paper, common diesel hydrotreating technologies at home and abroad were discussed, and the principle of each process was expounded. Then their application was listed, and the future development direction was analyzed.
With the increasingly stringent environmental protection, the demand for diesel quality is gradually increasing. Therefore, it is very important to develop an efficient and environmentally friendly diesel hydrotreating process. These technologies are used to improve the fraction of low-grade diesel oil to meet the standard of low sulfur and high sixteen alkane diesel products. In this paper, common diesel hydrotreating technologies at home and abroad were discussed, and the principle of each process was expounded. Then their application was listed, and the future development direction was analyzed.
引文
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[3]司云航,朱玉琴,邹蓉梅,等.我国车用柴油标准现状及发展趋势[J].石油与天然气化工,2014,43(1):82-86.
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[7]宁晓威.柴油加氢脱硫技术特点分析探讨[J].化工管理,2015(2):143.
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[14]赖全昌,张琰彬.灵活加氢改质MHUG-Ⅱ工艺在柴油加氢装置的应用[J].炼油技术与工程,2014,44(6):23-26.
[15]胡志海,蒋东红,石玉林,等.RICH工艺研究与开发[C].中国石油学会第四届石油炼制学术年会论文集,北京:石油工业出版社,2001:241-243.
[16]王欣.RICH技术在柴油加氢装置上的应用[J].石化技术与应用,2006,24(4):282-284.
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[20]张秀.影响催化裂化柴油十六烷值的因素与MCI技术[J].辽宁化工,2008,37(5):321-323.
[21]齐伟.FH-UDS催化剂在160万吨/年柴油加氢装置的工业应用[D].华东理工大学,2014.
[22]刘谦,李英玉,史振国,等.MCI工艺技术的工业应用[J].炼油技术与工程,2000,30(1):6-8.
[23]李振华.MCI柴油加氢改质技术工业应用[C].加入wto和中国科技与可持续发展--挑战与机遇、责任和对策,2002.
[24]Moser B R,Williams A,Haas M J,et al.Exhaust emissions and fuel properties of partially hydrogenated soybean oil methyl esters blended with ultra low sulfur diesel fuel[J].Fuel Processing Technology,2009,90(9):1122-1128.
[25]Laredo G C,Vega-Merino P M,Trejo-Zárraga F,et al.Denitrogenation of middle distillates using adsorbent materials towards ULSD production:A review[J].Fuel Processing Technology,2013,106(2):21-32.
[26]Min W.A unique way to make ultra low sulfur diesel[J].Korean Journal of Chemical Engineering,2002,19(4):601-606.
[27]Satterfield C N,Modell M,Mayer J F.Interactions between catalytic hydrodesulfurization of thiophene and hydrodenitrogenation of pyridine[J].Aiche Journal,2010,21(6):1100-1107.
[28]Lee S W,Ryu J W,Min W.SK Hydrodesulfurization(HDS)Pretreatment Technology for Ultralow Sulfur Diesel(ULSD)Production[J].Catalysis Surveys from Asia,2003,7(4):271-279.
[29]Christopher F Dean,Saudi Aramco,Jay L Ross.Improvements to increase fuel capacity and quality.Refining November[EB/OL].2002.http://www.eptq.com/.
[30]Stanislaus A,Marafi A,Rana M S.Recent advances in the science and technology of ultra low sulfur diesel(ULSD)production[J].Catalysis Today,2010,153(1):1-68.
[31]Ellis E S,Zaczepinski S,Halbert T R,et al.ULTRA LOW SULFURFUELS TECHNOLOGY[J].World Petroleum Congress,2000,16(6):11-15.
[32]Korsten H,Hoffmann U.Three‐phase reactor model for hydrotreating in pilot trickle‐bed reactors[J].Aiche Journal,1996,42(5):1350-1360.
[2]Peng C,Huang X,Liu T et al.Improve diesel quality through advanced hydroprocessing[J].Hydrocarbon Processing,2012,91(2):65-67.
[3]司云航,朱玉琴,邹蓉梅,等.我国车用柴油标准现状及发展趋势[J].石油与天然气化工,2014,43(1):82-86.
[4]方向晨,关明华,廖士纲.加氢精制[M].北京:中国石化出版社.
[5]张毓莹,蒋东红,辛靖,等.RIPP高选择性加氢改质系列技术开发及应用[C].中国石化加氢装置生产技术交流会,2012.
[6]王军强,阚宝训,林伊卫.MHUG-Ⅱ工艺生产国Ⅴ柴油的工业实践[J].炼油技术与工程,2016,46(2):19-22.
[7]宁晓威.柴油加氢脱硫技术特点分析探讨[J].化工管理,2015(2):143.
[8]Gao X,Shi Y,Zhang Z,et al.Study on production of low sulfur and low aromatics disel fuels[J].Petroleum Processing&Petrochemicals,1996,27(3):12-16.
[9]于海龙,李华明,徐国臣,等.中压加氢改质技术的工业应用[J].石油炼制与化工,1994,25(7):9-12.
[10]Jiang Donghong,Zhang Yuying,Hu Zhihai,et al.Medium-Pressure Hydro-upgrading(MHUG)Technology for Producing Clean Diesel Fuel[J].China Petroleum Processing&Petrochemical Technology,2012,14(1):1-7.
[11]蒋东红,任亮,辛靖,等.高选择性灵活加氢改质MHUG-Ⅱ技术的开发[J].石油炼制与化工,2012,43(6):25-30.
[12]赵东聪,苏福辉.柴油改质MHUG-Ⅱ装置生产国Ⅴ柴油前后运行状况浅析[J].广东化工,2016,43(21):133-136.
[13]宋鹏俊,阚宝训,赖全昌.柴油加氢改质MHUG-Ⅱ装置长周期运转分析及潜能预测[J].石油炼制与化工,2016,47(4):7-11.
[14]赖全昌,张琰彬.灵活加氢改质MHUG-Ⅱ工艺在柴油加氢装置的应用[J].炼油技术与工程,2014,44(6):23-26.
[15]胡志海,蒋东红,石玉林,等.RICH工艺研究与开发[C].中国石油学会第四届石油炼制学术年会论文集,北京:石油工业出版社,2001:241-243.
[16]王欣.RICH技术在柴油加氢装置上的应用[J].石化技术与应用,2006,24(4):282-284.
[17]赵玉琢,方向晨.一种提高催化柴油十六烷值的加氢改质工艺--MCI技术[J].加氢技术,1997,37(4):11-18.
[18]韩崇仁,方向晨,赵玉琢,等.催化裂化柴油一段加氢改质的新技术--MCI[J].石油炼制与化工,1999,30(9):1-5.
[19]黄新露,石培华,于淼.适应用户需求的催化柴油加氢改质技术[J].当代化工,2011,40(7):702-705,710.
[20]张秀.影响催化裂化柴油十六烷值的因素与MCI技术[J].辽宁化工,2008,37(5):321-323.
[21]齐伟.FH-UDS催化剂在160万吨/年柴油加氢装置的工业应用[D].华东理工大学,2014.
[22]刘谦,李英玉,史振国,等.MCI工艺技术的工业应用[J].炼油技术与工程,2000,30(1):6-8.
[23]李振华.MCI柴油加氢改质技术工业应用[C].加入wto和中国科技与可持续发展--挑战与机遇、责任和对策,2002.
[24]Moser B R,Williams A,Haas M J,et al.Exhaust emissions and fuel properties of partially hydrogenated soybean oil methyl esters blended with ultra low sulfur diesel fuel[J].Fuel Processing Technology,2009,90(9):1122-1128.
[25]Laredo G C,Vega-Merino P M,Trejo-Zárraga F,et al.Denitrogenation of middle distillates using adsorbent materials towards ULSD production:A review[J].Fuel Processing Technology,2013,106(2):21-32.
[26]Min W.A unique way to make ultra low sulfur diesel[J].Korean Journal of Chemical Engineering,2002,19(4):601-606.
[27]Satterfield C N,Modell M,Mayer J F.Interactions between catalytic hydrodesulfurization of thiophene and hydrodenitrogenation of pyridine[J].Aiche Journal,2010,21(6):1100-1107.
[28]Lee S W,Ryu J W,Min W.SK Hydrodesulfurization(HDS)Pretreatment Technology for Ultralow Sulfur Diesel(ULSD)Production[J].Catalysis Surveys from Asia,2003,7(4):271-279.
[29]Christopher F Dean,Saudi Aramco,Jay L Ross.Improvements to increase fuel capacity and quality.Refining November[EB/OL].2002.http://www.eptq.com/.
[30]Stanislaus A,Marafi A,Rana M S.Recent advances in the science and technology of ultra low sulfur diesel(ULSD)production[J].Catalysis Today,2010,153(1):1-68.
[31]Ellis E S,Zaczepinski S,Halbert T R,et al.ULTRA LOW SULFURFUELS TECHNOLOGY[J].World Petroleum Congress,2000,16(6):11-15.
[32]Korsten H,Hoffmann U.Three‐phase reactor model for hydrotreating in pilot trickle‐bed reactors[J].Aiche Journal,1996,42(5):1350-1360.