模板法制备三维多孔石墨烯及其复合材料研究进展
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摘要
三维多孔石墨烯及其复合材料作为一种功能材料在能量存储、光电器件、气体分离和存储、吸附和传感器等领域得到关注。模板法由于能够精确控制孔尺寸、形貌和结构得到广泛研究。综述了利用分子筛、沸石、SiO_2等硬模板,胶束、乳液、嵌段共聚物等软模板以及植物、粉末冶金、原位自牺牲等非传统模板制备三维多孔石墨烯及其复合材料的方法,并分析了各种方法的优缺点及材料性能。以期为三维多孔石墨烯及其复合材料的研究提供参考。
As a functional material,three-dimensional porous graphene and its composites have attracted attention in the fields of energy storage,optoelectronic devices,gas separation and storage,adsorption and sensors fields. The template methods were extensively studied due to its ability to precisely control pore size,morphology and structure. The template methods to prepare three-dimensional porous graphene and its composites were reviewed,including molecular sieve,zeolite and SiO_2 etc. hard templates,micelle,emulsion and block copolymer etc. soft templates,and plant,powder metallurgy and in-situ self-sacrifice etc. non-traditional templates as well. The advantages and disadvantages of various methods and the performance of materials were analyzed. To hope it can be used as a reference for the further study of three-dimensional porous graphene and its composites.
As a functional material,three-dimensional porous graphene and its composites have attracted attention in the fields of energy storage,optoelectronic devices,gas separation and storage,adsorption and sensors fields. The template methods were extensively studied due to its ability to precisely control pore size,morphology and structure. The template methods to prepare three-dimensional porous graphene and its composites were reviewed,including molecular sieve,zeolite and SiO_2 etc. hard templates,micelle,emulsion and block copolymer etc. soft templates,and plant,powder metallurgy and in-situ self-sacrifice etc. non-traditional templates as well. The advantages and disadvantages of various methods and the performance of materials were analyzed. To hope it can be used as a reference for the further study of three-dimensional porous graphene and its composites.
引文
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[14]陈鹏飞,张利,吴强.碳基材料模板法制备新材料的研究进展[J].材料导报,2016,30(7):115-120.
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[21]Wang Q,Yan J,Fan Z,et al.Mesoporous Polyaniline Film on Ultra-thin Graphene Sheets for High Performance Supercapacitors[J].Journal of Power Sources,2014,247(2):197-203.
[22]梁漫.石墨烯/介孔二氧化硅纳米复合材料的制备及其吸附性能研究[D].北京:北京化工大学,2015.
[23]Zeng Z,Huang X,Yin Z,et al.Fabrication of Graphene Nanomesh by Using an Anodic Aluminum Oxide Membrane as a Template[J].Advanced Materials,2012,24(30):4138-4142.
[24]Jung I,Jang H Y,Park S.Direct growth of Graphene Nanomesh Using a Au nano-network as a Metal Catalyst Via Chemical Vapor Deposition[J].Applied Physics Letters,2013,103(2):666-670.
[25]Wang Z L,Xu D,Wang H G,et al.In Situ Fabrication of Porous Graphene Electrodes for High-Performance Energy Storage[J].Acs Nano,2013,7(3):2422-2431.
[26]Fan Z,Liu Y,Yan J,et al.Template-Directed Synthesis of Pillared-Porous Carbon Nanosheet Architectures:High-Performance Electrode Materials for Supercapacitors[J].Advanced Energy Materials,2012,2(4):419-424.
[27]Zhang R,Chen Q,Zhen Z,et al.Cellulose-Templated Graphene Monoliths with Anisotropic Mechanical,Thermal,and Electrical Properties[J].Acs.Appl.Mater Interfaces,2015,7(34):19145-19152.
[28]王艳萍,郝红,韦雄雄,等.聚合物胶束的研究及应用进展[J].离子交换与吸附,2013,29(6):569-576.
[29]Huang X,Zhao Y,Ao Z,et al.Micelle-Template Synthesis of Nitrogen-Doped Mesoporous Graphene as an Efficient Metal-Free Electrocatalyst for Hydrogen Production[J].Sci.Rep.,2014,4:7557-7562.
[30]张心亚,孙志娟,黄洪,等.乳液聚合技术最新研究进展[J].合成材料老化与应用,2006,35(1):38-43.
[31]Zheng Z,Zheng X,Wang H,et al.Macroporous Graphene Oxide-Polymer Composite Prepared through Pickering High Internal Phase Emulsions[J].Applied Materials&Interfaces,2013,5(16):7974-7982.
[32]赵鹏飞,罗勇悦,何东宁,等.乳液模板-自组装法制备石墨烯/聚苯乙烯导电复合材料[J].功能材料,2013,44(19):2888-2891.
[33]Huang X,Sun B,Su D,et al.Soft-Template Synthesis of 3D Porous Graphene Foams with Tunable Architectures for Lithium-O2Batteries and Oil adsorption Applications[J].Journal of Materials Chemistry A,2014,2(21):7973-7979.
[34]程晓.基于嵌段共聚物模板的石墨烯负载银纳米结构调控及SERS性能研究[D].哈尔滨:哈尔滨工业大学,2014.
[35]Wang L,Sun L,Tian C,et al.A Novel Soft Template Strategy to Fabricate Mesoporous Carbon/Graphene Composites as High-performance Supercapacitor Electrodes[J].Rsc Advances,2012,2(22):8359-8367.
[36]Yang X,Liu A,Zhao Y,et al.Three-Dimensional Macroporous Polypyrrole-Derived Graphene Electrode Prepared by the Hydrogen Bubble Dynamic Template for Supercapacitors and Metal-Free Catalysts[J].Acs Appl Mater Interfaces,2015,7(42):23731-23740.
[37]何凤娟,钱君超,刘成宝,等.基于植物模板法制备高性能石墨烯/氧化锰复合材料及其电化学性能[J].机械工程材料,2017,41(1):34-37.
[38]Ryan G E,Pandit A S,Apatsidis D P.Porous Titanium Scaffolds Fabricated Using a Rapid Prototyping and Powder Metallurgy Technique[J].Biomaterials,2008,29(27):3625-3635.
[39]粉末冶金模板法制备三维石墨烯泡沫材料[J].传感器世界,2016,22(3):45-45.
[40]李纲,张文彦,迟煜頔,等.自牺牲模板法制备多孔MnCo2O4.5及其对高氯酸铵热分解的催化性能[J].稀有金属材料与工程,2017,46(3):824-828.
[41]Liu H H,Zhang H L,Xu H B,et al.In Situ Self-sacrificed Template Synthesis of Vanadium Nitride/Nitrogen-doped Graphene Nanocomposites for Electrochemical Capacitors[J].Nanoscale,2018,10:5246-5253.
[42]杨苗.冰模板法制备长程有序多孔材料[D].杭州:浙江大学,2017.
[43]Sun H,Xu Z,Gao C.Multifunctional,Ultra-Flyweight,Synergistically Assembled Carbon Aerogels[J].Advanced Materials,2013,25(18):2554-2560.
[44]高微微,赵妮芳,高超.冰模板法制备超轻石墨烯气凝胶及其组装单元尺寸效应[C].中国化学会2017全国高分子学术论文报告会摘要集-主题D:高分子物理化学.2017,209.
[2]唐多昌,李晓红,袁春华,等.机械剥离法制备高质量石墨烯的初步研究[J].西南科技大学学报,2010,25(3):16-18.
[3]张利锋,张金振,宋巧兰,等.水热法制备ZnO/石墨烯复合材料及其电化学性能研究[J].人工晶体学报,2014,43(12):3235-3240.
[4]郁万成,陈秀芳,孙丽,等.SiC衬底上外延石墨烯的氢插入及表征[J].人工晶体学报,2015,44(12):3384-3388.
[5]陈瑞灿,王海燕,韩永刚,等.氧化还原法制备石墨烯及其表征[J].材料导报,2012,26(12):114-117.
[6]史永贵,王东,张进成,等.化学气相沉积法生长石墨烯的研究[J].人工晶体学报,2014,43(7):001620-1625.
[7]Valcárcel V,Souto A,Guitián F.Development of Single-Crystalα-Al2O3Fibers by Vapor-Liquid-Solid Deposition(VLS)from Aluminum and Powdered Silica[J].Advanced Materials,1998,10(2):138-140.
[8]Yang T,Lin H,Zheng X,et al.Tailoring Pores in Graphene-Based Materials:from Generation to Applications[J].Journal of Materials Chemistry A,2017,5(32):16537-16558.
[9]陈丽娜,王德禧,谈述战,等.石墨烯超级电容器的研究进展及其应用[J].中国塑料,2014,28(6):8-18.
[10]虞祯君,王艳莉,邓洪贵,等.SnO2/石墨烯锂离子电池负极材料的制备及其电化学行为研究[J].无机材料学报,2013,28(5):515-520.
[11]钟轶良,莫再勇,杨莉君,等.改性石墨烯用作燃料电池阴极催化剂[J].化学进展,2013,25(5):717-725
[12]Wu D C,Xu F,Sun B,et al.Design and Preparation of Porous Polymers[J].Chemical Reviews,2012,112(7):3959-4015.
[13]李政杰.基于石墨烯模板的功能材料可控制备与储能研究[D].天津:天津大学,2016.
[14]陈鹏飞,张利,吴强.碳基材料模板法制备新材料的研究进展[J].材料导报,2016,30(7):115-120.
[15]Kang M,Yi S H,Lee H I,et al.Reversible Replication between Ordered Mesoporous Silica and Mesoporous Carbon[J].Chemical Communications,2002,8(17):1944-1945.
[16]董秀芳,曹端林,李裕,等.软模板法合成有序介孔材料的研究进展[J].化学工程师,2010,(5):43-45.
[17]钟玲,唐城,王斌,等.SAPO-34模板法制备多级孔石墨烯笼用作双功能氧还原/氧析出电催化剂(英文)[J].新型炭材料,2017,32(6):509-516.
[18]Corma A.From Microporous to Mesoporous Molecular Sieve Materials and Their Use in Catalysis[J].Cheminform,1997,28(52):2373-2420.
[19]Kim K,Lee T,Kwon Y,et al.Lanthanum-Catalysed Synthesis of Microporous 3D Graphene-like Carbons in a Zeolite Template[J].Nature,2016,535(7610):131-135.
[20]肖厚文.“模板”法制备石墨烯及其在超级电容器中的应用研究[D].福州:福建师范大学,2016.
[21]Wang Q,Yan J,Fan Z,et al.Mesoporous Polyaniline Film on Ultra-thin Graphene Sheets for High Performance Supercapacitors[J].Journal of Power Sources,2014,247(2):197-203.
[22]梁漫.石墨烯/介孔二氧化硅纳米复合材料的制备及其吸附性能研究[D].北京:北京化工大学,2015.
[23]Zeng Z,Huang X,Yin Z,et al.Fabrication of Graphene Nanomesh by Using an Anodic Aluminum Oxide Membrane as a Template[J].Advanced Materials,2012,24(30):4138-4142.
[24]Jung I,Jang H Y,Park S.Direct growth of Graphene Nanomesh Using a Au nano-network as a Metal Catalyst Via Chemical Vapor Deposition[J].Applied Physics Letters,2013,103(2):666-670.
[25]Wang Z L,Xu D,Wang H G,et al.In Situ Fabrication of Porous Graphene Electrodes for High-Performance Energy Storage[J].Acs Nano,2013,7(3):2422-2431.
[26]Fan Z,Liu Y,Yan J,et al.Template-Directed Synthesis of Pillared-Porous Carbon Nanosheet Architectures:High-Performance Electrode Materials for Supercapacitors[J].Advanced Energy Materials,2012,2(4):419-424.
[27]Zhang R,Chen Q,Zhen Z,et al.Cellulose-Templated Graphene Monoliths with Anisotropic Mechanical,Thermal,and Electrical Properties[J].Acs.Appl.Mater Interfaces,2015,7(34):19145-19152.
[28]王艳萍,郝红,韦雄雄,等.聚合物胶束的研究及应用进展[J].离子交换与吸附,2013,29(6):569-576.
[29]Huang X,Zhao Y,Ao Z,et al.Micelle-Template Synthesis of Nitrogen-Doped Mesoporous Graphene as an Efficient Metal-Free Electrocatalyst for Hydrogen Production[J].Sci.Rep.,2014,4:7557-7562.
[30]张心亚,孙志娟,黄洪,等.乳液聚合技术最新研究进展[J].合成材料老化与应用,2006,35(1):38-43.
[31]Zheng Z,Zheng X,Wang H,et al.Macroporous Graphene Oxide-Polymer Composite Prepared through Pickering High Internal Phase Emulsions[J].Applied Materials&Interfaces,2013,5(16):7974-7982.
[32]赵鹏飞,罗勇悦,何东宁,等.乳液模板-自组装法制备石墨烯/聚苯乙烯导电复合材料[J].功能材料,2013,44(19):2888-2891.
[33]Huang X,Sun B,Su D,et al.Soft-Template Synthesis of 3D Porous Graphene Foams with Tunable Architectures for Lithium-O2Batteries and Oil adsorption Applications[J].Journal of Materials Chemistry A,2014,2(21):7973-7979.
[34]程晓.基于嵌段共聚物模板的石墨烯负载银纳米结构调控及SERS性能研究[D].哈尔滨:哈尔滨工业大学,2014.
[35]Wang L,Sun L,Tian C,et al.A Novel Soft Template Strategy to Fabricate Mesoporous Carbon/Graphene Composites as High-performance Supercapacitor Electrodes[J].Rsc Advances,2012,2(22):8359-8367.
[36]Yang X,Liu A,Zhao Y,et al.Three-Dimensional Macroporous Polypyrrole-Derived Graphene Electrode Prepared by the Hydrogen Bubble Dynamic Template for Supercapacitors and Metal-Free Catalysts[J].Acs Appl Mater Interfaces,2015,7(42):23731-23740.
[37]何凤娟,钱君超,刘成宝,等.基于植物模板法制备高性能石墨烯/氧化锰复合材料及其电化学性能[J].机械工程材料,2017,41(1):34-37.
[38]Ryan G E,Pandit A S,Apatsidis D P.Porous Titanium Scaffolds Fabricated Using a Rapid Prototyping and Powder Metallurgy Technique[J].Biomaterials,2008,29(27):3625-3635.
[39]粉末冶金模板法制备三维石墨烯泡沫材料[J].传感器世界,2016,22(3):45-45.
[40]李纲,张文彦,迟煜頔,等.自牺牲模板法制备多孔MnCo2O4.5及其对高氯酸铵热分解的催化性能[J].稀有金属材料与工程,2017,46(3):824-828.
[41]Liu H H,Zhang H L,Xu H B,et al.In Situ Self-sacrificed Template Synthesis of Vanadium Nitride/Nitrogen-doped Graphene Nanocomposites for Electrochemical Capacitors[J].Nanoscale,2018,10:5246-5253.
[42]杨苗.冰模板法制备长程有序多孔材料[D].杭州:浙江大学,2017.
[43]Sun H,Xu Z,Gao C.Multifunctional,Ultra-Flyweight,Synergistically Assembled Carbon Aerogels[J].Advanced Materials,2013,25(18):2554-2560.
[44]高微微,赵妮芳,高超.冰模板法制备超轻石墨烯气凝胶及其组装单元尺寸效应[C].中国化学会2017全国高分子学术论文报告会摘要集-主题D:高分子物理化学.2017,209.
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