华东地区某市重点行业优控环境激素的筛选及分布特征
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摘要
为筛选华东地区某市重点行业优先控制环境激素,基于美国"内分泌干扰物筛选计划"、欧盟"内分泌干扰物共同体战略"等研究,本文整理得到重点关注环境激素名单,并对其在该市重点行业企业的生产使用情况进行了调查。结果表明,壬基酚、双酚、乙草胺等51种重点关注环境激素中,13种在重点行业企业的生产和使用中被涉及。根据上述13种环境激素的生产、使用量和涉及企业数等,进一步筛选得到4种建议区域优先控制环境激素,分别为苯乙烯、双酚A、邻苯二甲酸二乙酯和邻苯二甲酸二丁酯。从地区分布上看,4种建议区域优先控制环境激素的生产和使用主要集中在工业聚集区,主要涉及的行业为化学原料和化学制品制造业。研究结果为筛选优先控制环境激素、进一步识别其风险、重点突出地加强对其的管理和控制提供了理论依据。
In order to screen out environmental hormones for priority control in key industries of a city in East China, based on the US "Screening Plan for Endocrine Disruptors" and EU "Community Strategyfor Endocrine Disruptors", a list of environmental hormones including 51 chemicals was sorted out and the production and use of enterprises in key industries in the city were investigated. The results showedthat among key 51 environmental hormones, including nonylphenol, bisphenol and ethoxamine, 13 ofthem were involved in the production and use of investigated key industrial enterprises. Furthermore, fourof them, namely styrene, bisphenol A, diethyl phthalate and dibutyl phthalate, were screened as regionalpriority control environmental hormones, based on their production and consumption, as well as theenterprises involved in this city. The enterprises refer to four recommended regional priorityenvironmental hormones are mainly located in chemical industrial park, and mainly involving chemicalmaterials and chemical products industry. The results provide a theoretical basis for screening environmental hormones, further identifying their risks, and emphatically strengthening their management and control.
In order to screen out environmental hormones for priority control in key industries of a city in East China, based on the US "Screening Plan for Endocrine Disruptors" and EU "Community Strategyfor Endocrine Disruptors", a list of environmental hormones including 51 chemicals was sorted out and the production and use of enterprises in key industries in the city were investigated. The results showedthat among key 51 environmental hormones, including nonylphenol, bisphenol and ethoxamine, 13 ofthem were involved in the production and use of investigated key industrial enterprises. Furthermore, fourof them, namely styrene, bisphenol A, diethyl phthalate and dibutyl phthalate, were screened as regionalpriority control environmental hormones, based on their production and consumption, as well as theenterprises involved in this city. The enterprises refer to four recommended regional priorityenvironmental hormones are mainly located in chemical industrial park, and mainly involving chemicalmaterials and chemical products industry. The results provide a theoretical basis for screening environmental hormones, further identifying their risks, and emphatically strengthening their management and control.
引文
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[25]黄春,周兴翠,钱益斌.海南省化学品生产使用情况调查结果及相关建议[J].化工管理, 2017(34):20-22.HUANG C, ZHOU X C, QIAN Y B. Investigation results and relevantsuggestions of chemical production in Hainan province[J]. ChemicalEnterprise Management, 2017(34):20-22.
[26] XU G, MA S H, TANG L, et al. Occurrence, fate and risk assessmentof selected endocrine disrupting chemicals in wastewater treatmentplants and receiving river of Shanghai, China[J]. EnvironmentalScience and Pollution Research, 2018, 23(24):25442-25450.
[27]王兴和,周颖,王霞,等.上海市水环境中主要酚类污染物筛选和评价[J].复旦学报(医学版), 2012, 39(3):221-237.WANG X H, ZHOU Y, WANG X, et al. Screening and assessing thephenols in water environment of Shanghai city[J]. Fudan UniversityJournal of Medical Sciences, 2012, 39(3):221-237.
[28] US Environmental Protection Agency. Ecotox knowledgebase[EB/OL].[2018-09-13]. https://cfpub.epa.gov/ecotox/index.cfm.
[29]邵海洋.上海市典型介质中邻苯二甲酸酯类环境激素的研究[D].上海:上海大学,2013.SHAO H Y. Study on phthalic acid ethers of environmental hormone invarious typical environmental matrices of Shanghai[D]. Shanghai:Shanghai University, 2013.
[30]吴明红,王扶琳,杨雪霞,等.上海地区水环境中邻苯二甲酸酯类污染物的浓度水平及分布特征[J].上海大学学报(自然科学版), 2016(2):105-113.WU M H, WANG F L, YANG X X, et al. Concentration levels anddistribution features of PAEs in water environment in Shanghai[J].Journal of Shanghai University(Natural Science Edition), 2016(2):105-113.
[2] US Environmental Protection Agency(USEPA). Special report onenvironmental endocrine disruption:an effects assessment and analysis[R]. Washington DC:Office of Research and Development, 1997.
[3] BOWERMAN W W, BEST D A, GRUBBT G, et al. Assessment ofenvironmental endocrine disruptors in bald eagles of the Great Lakes[J]. Chemosphere, 2000, 41(10):1569-1574.
[4] DE COSTER S, VAN LAREBEKE N. Endocrine-disruptingchemicals:associated disorders and mechanisms of action[J]. Journalof Environmental and Public Health, 2012(8):713696.
[5] VAN ZIJI M C, ANECKHAHN N H, SWART P, et al. Estrogenicactivity, chemical levels and health risk assessment of municipaldistribution point water from pretoria and Cape Town, South Africa[J].Chemosphere, 2017, 186:305.
[6] MINH T L T, DAN N P, QUOC T D, et al. Presence of e-EDCs insurface water and effluents of pollution sources in sai gon and dong NaiRiver Basin[J]. Sustainable Environment Research, 2016, 26(1):20-27.
[7] LIU Y H, ZHANG S H, JI G X, et al. Occurrence, distribution and riskassessment of suspected endocrine-disrupting chemicals in surfacewater and suspended particulate matter of Yangtze river(NanjingSection)[J]. Ecotoxicology&Environmental Safety, 2017, 135:90-97.
[8] LI Z, XIANG X, LI M, et al. Occurrence and risk assessment ofpharmaceuticals and personal care products and endocrine disruptingchemicals in reclaimed water and receiving groundwater in China[J].Ecotoxicology&Environmental Safety, 2015, 119:74-80.
[9] DODGEN L K, LI J, WU X, et al. Transformation and removalpathways of four common PPCP/EDCs in soil[J]. EnvironmentalPollution, 2014, 193:29-36.
[10] SUN J T. PAN L L, ZHAN Y, et al. Contamination of phthalate esters,organochlorine pesticides and polybrominated diphenyl ethers inargricultural soil from the Yangtze River Delta of China[J]. Science ofthe Total Environment, 2016, 544:670-676.
[11] TEIL M J, MOREAU-GUIGON E, BLANCHARD M, et al. Endocrinedisrupting compounds in gaseous and particulate outdoor air phaseaccording to environmental factors[J]. Chemosphere, 2015, 146:94.
[12] ZENG F, LIN Y, CUI K, et al. Atmospheric deposition of phthalateesters in a subtropical city[J]. Atmospheric Environment, 2010, 44(6):834-840.
[13] KUMAR V, MAJUMDAR C, ROY P. Effects of endocrine disruptingchemicals from leather from leather industry effluents on malereproductive system[J]. Journal of Steroid Biochemistry&MolecularBiology, 2008, 111(3/4/5):208-216.
[14] STAOLES C A, PETERSON D R, PARKERTON T F, et al. Theenvironmental fate of phthalate esters:a literature review[J].Chemosphere, 1997, 35(4):667-749.
[15] HERMABESSIERE L, DEHAUT A, PAUL-PONT I, et al. Occurrenceand effects of plastic additives on marine environments and organisms:a review[J]. Chemosphere, 2017, 182:781-793.
[16] PIVENKO K, ERIKSEN M K, MARTIN-FERNáNDEZ J A, et al.Recycling of plastic waste:presence of phthalates in plastics fromhouseholds and industry[J]. Waste Management, 2016, 54:44-52.
[17] VANDENBERG L N, HAUSER R, MAECUS M, et al. Humanexposure to bisphenol a(BPA)[J]. Reproductive Toxicology, 2007, 24(2):139-177.
[18] LEE H B, PEART T E, GRIS G, et al. Endocrine-disrupting chemicalsin industrial wastewater samples in Toronto, Ontario[J]. Water QualityResearch Journal of Canada, 2002, 37(2):459-472.
[19] US Environmental Protection Agency. Final second list of chemicalsfor tier 1 screening[R]. Washington DC:US EPA, 2014.
[20] Japan Environment Agency. Strategic program on environmentalendocrine disruptors’98(SPEED’98)[R]. Ministry of the Environment,1998.
[21] EU Commission. Communication from the Commission to the Counciland the European Parliament on the implementation of the CommunityStrategy for Endocrine Disrupters—a range of substances suspected ofinterferring with the hormone ystems of humans and wildlife[R].Commission of the European Communities, 1999.
[22] World Health Organization(WHO). State of the scinece of endocrinedisrupting chemicals-2012[R]. United Nations EnvironmentProgramme(UNEP), 2012.
[23] Our Stolen Future. Widespread pollutants with Endocrine-disruptingeffects[EB/OL]. World Wildlife Fund, 2008. http://www.ourstolenfuture.com/basics/chemlist.htm.
[24]杜艳,郝华.安徽省环境激素类化学品调查成果及对策建议[J].广东化工, 2017, 44(6):92-94.DU Y, HAO L. Achievement and suggestion of environmentalendocrine investigation for Anhui province[J]. Guangdong ChemicalIndustry, 2017, 44(6):92-94.
[25]黄春,周兴翠,钱益斌.海南省化学品生产使用情况调查结果及相关建议[J].化工管理, 2017(34):20-22.HUANG C, ZHOU X C, QIAN Y B. Investigation results and relevantsuggestions of chemical production in Hainan province[J]. ChemicalEnterprise Management, 2017(34):20-22.
[26] XU G, MA S H, TANG L, et al. Occurrence, fate and risk assessmentof selected endocrine disrupting chemicals in wastewater treatmentplants and receiving river of Shanghai, China[J]. EnvironmentalScience and Pollution Research, 2018, 23(24):25442-25450.
[27]王兴和,周颖,王霞,等.上海市水环境中主要酚类污染物筛选和评价[J].复旦学报(医学版), 2012, 39(3):221-237.WANG X H, ZHOU Y, WANG X, et al. Screening and assessing thephenols in water environment of Shanghai city[J]. Fudan UniversityJournal of Medical Sciences, 2012, 39(3):221-237.
[28] US Environmental Protection Agency. Ecotox knowledgebase[EB/OL].[2018-09-13]. https://cfpub.epa.gov/ecotox/index.cfm.
[29]邵海洋.上海市典型介质中邻苯二甲酸酯类环境激素的研究[D].上海:上海大学,2013.SHAO H Y. Study on phthalic acid ethers of environmental hormone invarious typical environmental matrices of Shanghai[D]. Shanghai:Shanghai University, 2013.
[30]吴明红,王扶琳,杨雪霞,等.上海地区水环境中邻苯二甲酸酯类污染物的浓度水平及分布特征[J].上海大学学报(自然科学版), 2016(2):105-113.WU M H, WANG F L, YANG X X, et al. Concentration levels anddistribution features of PAEs in water environment in Shanghai[J].Journal of Shanghai University(Natural Science Edition), 2016(2):105-113.