摘要
研究了EVA(乙烯-醋酸乙烯共聚物)对天然橡胶(NR)/丁腈橡胶(NBR)并用胶硫化特性、力学性能、阻尼性能、压缩生热的影响。结果表明:随着EVA含量的增多,NR/NBR并用胶的硫化速度先升后降;拉伸强度降低,撕裂强度则先增加后下降,硬度增加,回弹性降低;NR/NBR并用胶在拉伸/压缩-恢复过程中的HED和HLE均先减少后增大; DMA谱图中NR与NBR相损耗峰均移向低温,有效阻尼温域拓宽;压缩永久变形和疲劳温升增加。
The effects of EVA(ethylene-vinyl acetate copolymer) on the vulcanization properties,mechanical properties, damping properties and compression heat generation of natural rubber(NR)/nitrile rubber(NBR) were investigated in this paper. The results show that with the increase of EVA content,the vulcanization rate of NR/NBR blended rubber increased first and then decreased; The tensile strength decreased, and the tear strength increased first and then decreased; the hardness increased, and the rebound resilience decreased; The HED and HLE of the NR/NBR blended rubber first reduced and then increased during the stretching/compression-recovery process; In the DMA spectrum, the loss peaks of NR and NBR phase shift to low temperature, and the effective damping temperature domain is broadened;compression set and fatigue temperature rise increased.
引文
[1] Li M,Li Y,Zhang J, et al. Effect of compatibilizers on the miscibility of natural rubber/silicone rubber blends[J].Polymer Engineering&Science,2014,54(2):355-363.
[2]罗权焜,郭建华.几种合成像胶的并用、硫化特性与性能的研究[J].特种像胶制品,2007,28(2):5-13.
[3]牛凯晶.天然橡胶/丁腈橡胶/环氧化天然橡胶复合材料及其在隔震支座的应用[D].北京化工大学,2016.
[4] Zhao X, Yang J,Zhao D,et al. Natural rubber/nitrile butadiene rubber/hindered phenol composites with highdamping properties[J]. International Journal of Smart&Nano Materials,2015, 6(4):239-250.
[5] Onyeagoro, G. N.(2012). Effect of zinc oxide level and blendratio on vulcanizate properties of blend of natural rubber and acrylonitrile-butadiene rubber in the presence of epoxidized natural rubber. Academic Research International 1),499-509.
[6]王文福.EVA橡胶的性能与共聚物中醋酸乙烯酯含量的关系[J].世界橡胶工业,2004, 31(2):9-12.
[7]张敬,王醴均,张纯,等.天然橡胶/EVA发泡复合材料发泡质量及力学性能的分析[J].高分子材料科学与工程,2014,30(3):53-58.
[8]单博,张小萍.乙烯-醋酸乙烯共聚物改性聚氯乙烯的研究[J].中国塑料,2018(2).
[9]杨钢,李启成,李雅明,等.乙烯-乙酸乙烯酯共聚物(EVA)的性能及应用[J].胶体与聚合物,2009, 27(3):45-46.