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中温固体氧化物燃料电池La_(0.8)Sr_(0.2)MnO_(3-)Ba_(0.5)Sr_(0.5)Co_(0.8)Fe_(0.2)O_(3-σ)阴极的制备研究
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  • 英文篇名:Preparation and Electrochemical Properties of La_(0.8)Sr_(0.2)MnO_(3-σ) Coated Ba_(0.5)Sr_(0.5)Co_(0.8)Fe_(0.2)O_(3-σ) Cathodes for Intermediate Temperature Solid Oxide Fuel Cells
  • 作者:刘波 ; 贾礼超 ; 欧阳瑞丰 ; 李箭
  • 英文作者:LIU Bo;JIA Lichao;OUYANG Ruifeng;LI Jian;School of Materials Science and Engineering,Huazhong University of Science and Technology;Department of Material Science and Engineering, Jingdezhen Ceramic Institute;
  • 关键词:固体氧化物燃料电池 ; LSM-BSCF ; 抗CO_2气体毒化
  • 英文关键词:solid oxide fuel cells;;LSM-BSCF;;ant-CO_2 poisoning
  • 中文刊名:TCXB
  • 英文刊名:Journal of Ceramics
  • 机构:华中科技大学材料科学与工程学院;景德镇陶瓷大学材料科学与工程学院;
  • 出版日期:2019-02-15
  • 出版单位:陶瓷学报
  • 年:2019
  • 期:v.40
  • 基金:国家自然科学基金(51472099)
  • 语种:中文;
  • 页:TCXB201901027
  • 页数:4
  • CN:01
  • ISSN:36-1205/TS
  • 分类号:107-110
摘要
使用固溶包覆法成功合成了La_(0.8)Sr_(0.2)MnO_(3-σ)(LSM)包覆Ba_(0.5)Sr_(0.5)Co_(0.8)Fe_(0.2)O_(3-σ)(BSCF)的LSM-BSCF复合粉体,分析了复合粉体的物相组成,形貌结构,抗CO_2气体毒化能力以及相应电极电化学性能,结果表明所制备的粉体成相良好,具有较好的抗CO_2毒化性能,而电化学性能有所降低。
        La_(0.8)Sr_(0.2)MnO_(3-σ) coated Ba_(0.5)Sr_(0.5)Co_(0.8)Fe_(0.2)O_(3-σ)(LSM-BSCF) composite powders was successfully synthesized by solid-solution method. Some property of material was investigated, such as the phase composition, morphology, ability of ant-CO_2 gas poisoning, and electrochemical performance. The result showed the material have good crystal structure, well ability of ant-CO_2 gas poisoning, and the electrochemical performance is reduced.
引文
[1]A.BOUDGHENE STAMBOULI.E.T.Solid oxide fuel cells(SOFCs):a review of an environmentally clean and efficient source of energy[J].Renewable and Sustainable Energy Reviews,2002,6:433-455.
    [2]ADLER S B.Factors Governing Oxygen Reduction in Solid Oxide Fuel Cell Cathodes[J].Chem.Rev,2004,104:4791-4843.
    [3]ZONGPING SHAO,S M H.A high-performance cathode for the next generation of solid-oxide fuel cells[J].Nature,2004,431:170-173.
    [4]YAN A,CHENG M,DONG Y,et al.Investigation of a Ba0.5Sr0.5Co0.8Fe0.2O3-δbased cathode IT-SOFC[J].Applied Catalysis B:Environmental,2006,66(1-2):64-71.
    [5]WANG S,LU X,LIU M.Electrocatalytic properties of La 0.9 Sr 0.1MnO3-based electrodes for oxygen reduction[J].Journal of Solid State Electrochemistry,2002,6(6):384-390.

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