摘要
使用固溶包覆法成功合成了La_(0.8)Sr_(0.2)MnO_(3-σ)(LSM)包覆Ba_(0.5)Sr_(0.5)Co_(0.8)Fe_(0.2)O_(3-σ)(BSCF)的LSM-BSCF复合粉体,分析了复合粉体的物相组成,形貌结构,抗CO_2气体毒化能力以及相应电极电化学性能,结果表明所制备的粉体成相良好,具有较好的抗CO_2毒化性能,而电化学性能有所降低。
La_(0.8)Sr_(0.2)MnO_(3-σ) coated Ba_(0.5)Sr_(0.5)Co_(0.8)Fe_(0.2)O_(3-σ)(LSM-BSCF) composite powders was successfully synthesized by solid-solution method. Some property of material was investigated, such as the phase composition, morphology, ability of ant-CO_2 gas poisoning, and electrochemical performance. The result showed the material have good crystal structure, well ability of ant-CO_2 gas poisoning, and the electrochemical performance is reduced.
引文
[1]A.BOUDGHENE STAMBOULI.E.T.Solid oxide fuel cells(SOFCs):a review of an environmentally clean and efficient source of energy[J].Renewable and Sustainable Energy Reviews,2002,6:433-455.
[2]ADLER S B.Factors Governing Oxygen Reduction in Solid Oxide Fuel Cell Cathodes[J].Chem.Rev,2004,104:4791-4843.
[3]ZONGPING SHAO,S M H.A high-performance cathode for the next generation of solid-oxide fuel cells[J].Nature,2004,431:170-173.
[4]YAN A,CHENG M,DONG Y,et al.Investigation of a Ba0.5Sr0.5Co0.8Fe0.2O3-δbased cathode IT-SOFC[J].Applied Catalysis B:Environmental,2006,66(1-2):64-71.
[5]WANG S,LU X,LIU M.Electrocatalytic properties of La 0.9 Sr 0.1MnO3-based electrodes for oxygen reduction[J].Journal of Solid State Electrochemistry,2002,6(6):384-390.